Annealing effects on structural and magnetic properties of α-Fe2O3 nanoparticles

被引:27
作者
Vasquez-Mansilla, M
Zysler, RD [1 ]
Arciprete, C
Dimitrijewits, M
Rodriguez-Sierra, D
Saragovi, C
机构
[1] Ctr Atom Bariloche, RA-8400 SC Bariloche, Rio Negro, Argentina
[2] Inst Balseiro, RA-8400 SC Bariloche, Rio Negro, Argentina
[3] Ctr Atom Constituyentes, Dept Fis, RA-1650 Buenos Aires, DF, Argentina
关键词
nanoparticles; nanocrystallization; hematite; annealing effect;
D O I
10.1016/S0304-8853(00)00858-1
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The effect of transformations induced by annealing on the structure and magnetic properties of alpha -Fe2O3 antiferromagnetic nanoparticles synthesized by chemical route has been investigated by transmission electron microscopy, magnetization measurements and Mossbauer spectroscopy. Annealing of these samples re-crystallize the nanoparticles without changing its mean size modifying the crystalline anisotropy energy of the nanoparticles leading to a change in the reversible-irreversible regime and in the Morin transition behaviour. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:1907 / 1909
页数:3
相关论文
共 7 条
[1]   MORIN TEMPERATURE OF ANNEALED SUBMICRONIC ALPHA-F2O3 PARTICLES [J].
AMIN, N ;
ARAJS, S .
PHYSICAL REVIEW B, 1987, 35 (10) :4810-4811
[2]  
ARTMAN JO, 1965, PHYS REV A, V138, P912
[3]   Interplay of surface conditions, particle size, stoichiometry, cell parameters, and magnetism in synthetic hematite-like materials [J].
Dang, MZ ;
Rancourt, DG ;
Dutrizac, JE ;
Lamarche, G ;
Provencher, R .
HYPERFINE INTERACTIONS, 1998, 117 (1-4) :271-319
[4]   *PROPRIETES MAGNETIQUES DU SESQUIOXYDE DE FER FE2O3-ALPHA [J].
GUILLAUD, C .
JOURNAL DE PHYSIQUE ET LE RADIUM, 1951, 12 (03) :489-491
[5]   NEUTRON DIFFRACTION BY PARAMAGNETIC AND ANTIFERROMAGNETIC SUBSTANCES [J].
SHULL, CG ;
STRAUSER, WA ;
WOLLAN, EO .
PHYSICAL REVIEW, 1951, 83 (02) :333-345
[6]  
VANDENBERGHE RE, 1991, DIST3E PROGRAM BASED
[7]   Magnetic interaction evidence in α-Fe2O3 nanoparticles by magnetization and Mossbauer measurements [J].
Vasquez-Mansilla, M ;
Zysler, RD ;
Apciprete, C ;
Dimitrijewits, MI ;
Saragovi, C ;
Greneche, JM .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1999, 204 (1-2) :29-35