Catalytic uses of helicenes displaying phosphorus functions

被引：34

作者：

Demmer, Charles S. ^{[1
]}

Voituriez, Arnaud ^{[1
]}

Marinetti, Angela ^{[1
]}

机构：

[1] Univ Paris Saclay, Univ Paris Sud, Inst Chim Subst Nat, CNRS,UPR 2301, 1 Av La Terrasse, F-91198 Gif Sur Yvette, France

来源：

COMPTES RENDUS CHIMIE | 2017年 / 20卷 / 08期

关键词：

Helical chirality; Phosphorus ligands; Organocatalysis; Gold catalysis; Phosphahelicenes; ENANTIOSELECTIVE GOLD-CATALYSIS; 2+2+2 CYCLOISOMERIZATION; PHOTOPHYSICAL PROPERTIES; ASYMMETRIC REACTIONS; CHIRAL PHOSPHINES; 3+2 CYCLIZATIONS; COMPLEXES; LIGANDS; OXIDES; UNITS;

D O I：

10.1016/j.crci.2017.04.002

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review presents an updated state of art of the catalytic uses of chiral phosphorus compounds characterized by a helical scaffold as the key stereogenic element of their structures. These include both helical scaffolds with appended phosphorus functions and helical scaffolds with embedded phosphorus-containing rings (phosphahelicenes). Catalytic applications of helical phosphines in both transition metal catalysis and organocatalysis are presented. (C) 2017 Academie des sciences. Published by Elsevier Masson SAS.

引用

页码：860 / 879

页数：20

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