Cerium(IV) Orthophosphates (Review)

被引：10

作者：

Kozlova, T. O. ^{[1
]}

Baranchikov, A. E. ^{[1
]}

Ivanov, V. K. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2021年 / 66卷 / 12期

基金：

俄罗斯基础研究基金会;

关键词：

rare earth elements; phosphates; crystal structure; amorphous compounds; PHOSPHATE-HYDROGENPHOSPHATE HYDRATE; CRYSTALLINE INSOLUBLE SALTS; ION-EXCHANGE BEHAVIOR; RARE-EARTH-ELEMENTS; HYDROTHERMAL SYNTHESIS; FIBROUS CERIUM(IV); HYDROGEN PHOSPHATE; THORIUM PHOSPHATE; ADSORPTION BEHAVIOR; ZIRCONIUM-PHOSPHATES;

D O I：

10.1134/S003602362112010X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The review analyzes the data on the composition, structure, and properties of amorphous and crystalline cerium(IV) orthophosphates published between 1882 and 2020. The review includes information on Ce(IV) complexation in aqueous solutions, formation conditions and characteristics of amorphous inorganic and organo-inorganic cerium(IV) hydrogen orthophosphates, and structural diversity of crystalline cerium(IV) orthophosphates. Formation conditions and structure of the closest chemical analogs of cerium(IV) orthophosphates, Group IV metal and actinide (thorium and uranium) orthophosphates, have been compared for the first time; the comparison provided a basis to assess the possibilities to prepare isostructural cerium(IV) compounds unknown to date.

引用

页码：1761 / 1778

页数：18

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