Synthesis and characterization of the gold(I) tris(ethylene) complex [AU(C2H4)3][SbF6]

被引：77

作者：

Dias, H. V. Rasika ^{[1
]}

Fianchini, Mauro ^{[1
]}

Cundari, Thomas R. ^{[2
]}

Campana, Charles F. ^{[3
]}

机构：

[1] Univ Texas Arlington, Dept Chem & Biochem, Arlington, TX 76019 USA

[2] Univ N Texas, Dept Chem, CASCaM, Denton, TX 76203 USA

[3] Bruker AXS Inc, Single Crystal Diffract, Madison, WI 53711 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 03期

关键词：

alkene ligands; density functional calculations; gold; pi interactions; X-ray diffraction;

D O I：

10.1002/anie.200703515

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ethylene el dorado: Gold(I) unusually takes up three ethylene molecules in a spoked-wheel arrangement (see picture). The complex was synthesized as the hexafluoroantimonate salt and structurally characterized. (Figure Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：556 / 559

页数：4

共 49 条

[1] Gold is smaller than silver, crystal structures of [bis(trimesitylphosphine)gold(I)] and [bis(trimesitylphosphine)silver(I)] tetrafluoroborate
Bayler, A
Schier, A
Bowmaker, GA
Schmidbaur, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (29) : 7006 - 7007
[2] Choice of coordination number in d10 complexes of group 11 metals
Carvajal, MA
Novoa, JJ
Alvarez, S
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (05) : 1465 - 1477
[3] OLEFIN CO-ORDINATION COMPOUNDS .3. INFRA-RED SPECTRA AND STRUCTURE - ATTEMPTED PREPARATION OF ACETYLENE COMPLEXES
CHATT, J
DUNCANSON, LA
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1953, (OCT): : 2939 - 2947
[4] Monomeric silver(I) β-diketiminate complexes
Chiong, Hendrich A.
Daugulis, Olafs
[J]. ORGANOMETALLICS, 2006, 25 (17) : 4054 - 4057
[5] Reaction of gold(III) oxo complexes with alkenes.: Synthesis of unprecedented gold alkene complexes, [Au(N,N)(alkene)][PF6].: Crystal structure of [Au(bipyip)(η2-CH2=CHPh)][PF6] (bipyip=6-isopropyl-2,2′-bipyridine)
Cinellu, MA
Minghetti, G
Stoccoro, S
Zucca, A
Manassero, M
[J]. CHEMICAL COMMUNICATIONS, 2004, (14) : 1618 - 1619
[6] Reactions of gold(III) oxo complexes with cyclic alkenes
Cinellu, MA
Minghetti, G
Cocco, T
Stoccoro, S
Zucca, A
Manassero, M
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (42) : 6892 - 6895
[7] Synthesis and properties of gold alkene complexes.: Crystal structure of [Au(bipyoXyl)(η2-CH2=CHPh)](PF6) and DFT calculations on the model cation [Au(bipy)(η2-CH2=CH2)]
Cinellu, Maria A.
Minghetti, Giovanni
Cocco, Fabio
Stoccoro, Sergio
Zucca, Antonio
Manassero, Mario
Arca, Massimiliano
[J]. DALTON TRANSACTIONS, 2006, (48) : 5703 - 5716
[8] THE VIBRATIONAL-SPECTRA AND STRUCTURE OF TRIS(ETHYLENE)METALS
CSASZAR, P
GOGGIN, PL
MINK, J
SPENCER, JL
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 379 (03) : 337 - 349
[9] Double hydrogen bond- and pi-pi-stacking-assembled two-dimensional copper(I) complex of 2-hydroxyquinoxaline
Dai, J
Yamamoto, M
KurodaSowa, T
Maekawa, M
Suenaga, Y
Munakata, M
[J]. INORGANIC CHEMISTRY, 1997, 36 (12) : 2688 - 2690
[10] Dioxygen activation by a neutral β-diketiminato copper(I) ethylene complex
Dai, XL
Warren, TH
[J]. CHEMICAL COMMUNICATIONS, 2001, (19) : 1998 - 1999

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