Synthesis and characterization of the gold(I) tris(ethylene) complex [AU(C2H4)3][SbF6]

被引：77
|
作者：
Dias, H. V. Rasika [1 ]
Fianchini, Mauro [1 ]
Cundari, Thomas R. [2 ]
Campana, Charles F. [3 ]
机构：
[1] Univ Texas Arlington, Dept Chem & Biochem, Arlington, TX 76019 USA
[2] Univ N Texas, Dept Chem, CASCaM, Denton, TX 76203 USA
[3] Bruker AXS Inc, Single Crystal Diffract, Madison, WI 53711 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 03期
关键词：
alkene ligands; density functional calculations; gold; pi interactions; X-ray diffraction;
D O I：
10.1002/anie.200703515
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ethylene el dorado: Gold(I) unusually takes up three ethylene molecules in a spoked-wheel arrangement (see picture). The complex was synthesized as the hexafluoroantimonate salt and structurally characterized. (Figure Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：556 / 559
页数：4
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