Rational design of macrocellular silica scaffolds obtained by a tunable sol-gel foaming process

被引:86
作者
Carn, F
Colin, A
Achard, MF
Deleuze, H
Saadi, Z
Backov, R
机构
[1] CNRS, Ctr Rech Paul Pascal, UPR 8641, F-33600 Pessac, France
[2] Univ Bordeaux 1, Lab Chim Organ & Organomet, UMR 5802, CNRS, F-33045 Talence, France
关键词
D O I
10.1002/adma.200306067
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A technique that uses a non-static patterning method has been employed for rational design toward macrocellular silica scaffolds (see Figure). The technique allows complete control over the width, length, and curvature of the plateau borders of the silica foam. Furthermore, this macroscale void space structuration is associated with secondary micro- and mesoscale porosity thus reaching hierarchically organized monolith-type materials.
引用
收藏
页码:140 / +
页数:6
相关论文
共 32 条
  • [1] ELECTRICAL-CONDUCTIVITY AND THE DISTRIBUTION OF LIQUID IN POLYHEDRAL FOAM
    AGNIHOTRI, AK
    LEMLICH, R
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1981, 84 (01) : 42 - 46
  • [2] TEMPLATING OF MESOPOROUS MOLECULAR-SIEVES BY NONIONIC POLYETHYLENE OXIDE SURFACTANTS
    BAGSHAW, SA
    PROUZET, E
    PINNAVAIA, TJ
    [J]. SCIENCE, 1995, 269 (5228) : 1242 - 1244
  • [3] Morphosynthesis of macrocellular mesoporous silicate foams
    Bagshaw, SA
    [J]. CHEMICAL COMMUNICATIONS, 1999, (09) : 767 - 768
  • [4] A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES
    BECK, JS
    VARTULI, JC
    ROTH, WJ
    LEONOWICZ, ME
    KRESGE, CT
    SCHMITT, KD
    CHU, CTW
    OLSON, DH
    SHEPPARD, EW
    MCCULLEN, SB
    HIGGINS, JB
    SCHLENKER, JL
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) : 10834 - 10843
  • [5] Brinker C.J., 1990, SOL GEL SCI
  • [6] Porous inorganic materials
    Brinker, CJ
    [J]. CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 1996, 1 (06) : 798 - 805
  • [7] Generalised syntheses of ordered mesoporous oxides:: the atrane route
    Cabrera, S
    El Haskouri, J
    Guillem, C
    Latorre, J
    Beltrán-Porter, A
    Beltrán-Porter, D
    Marcos, MD
    Amorós, P
    [J]. SOLID STATE SCIENCES, 2000, 2 (04) : 405 - 420
  • [8] Anisotropy of draining foams
    Carrier, V
    Colin, A
    [J]. LANGMUIR, 2002, 18 (20) : 7564 - 7570
  • [9] CARRIER V, 2002, NONLINEAR SOFT MATTE, V65
  • [10] Materials chemistry - Macroporous crystalline vanadium oxide foam
    Chandrappa, GT
    Steunou, N
    Livage, J
    [J]. NATURE, 2002, 416 (6882) : 702 - 702