Electro-optical triple-channel sensing of metal cations via multiple signalling patterns

被引:85
作者
Jiménez, D [1 ]
Martínez-Máñez, R [1 ]
Sancenón, F [1 ]
Soto, J [1 ]
机构
[1] Univ Politecn Valencia, Dept Quim, GDDS, E-46071 Valencia, Spain
关键词
chemosensors; electro-optical sensing; triple signalling; Ph2+ detection; Hg2+ detection;
D O I
10.1016/j.tetlet.2003.11.123
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
We described two molecular systems containing tricyanovinyl dyes as signalling Subunits and crown ether macrocycles Lis binding sites, which act as triple-channel sensing receptors. Signalling was observed through UV-vis, fluorescence and electrochemical measurements. With these three techniques sensing of certain metal cations was achieved via multiple signalling patterns. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1257 / 1259
页数:3
相关论文
共 20 条
[1]   A NEW CHROMOPHORIC AND REDOX-RESPONSIVE IONOPHORE CONTAINING A TRICYANOVINYL MOIETY [J].
BEER, PD ;
SIKANYIKA, H .
POLYHEDRON, 1990, 9 (14) :1747-1749
[2]   A two-channel molecular dosimeter for the optical detection of copper(II) [J].
Boiocchi, M ;
Fabbrizzi, L ;
Licchelli, M ;
Sacchi, D ;
Vázquez, M ;
Zampa, C .
CHEMICAL COMMUNICATIONS, 2003, (15) :1812-1813
[3]   ION-RESPONSIVE FLUORESCENT COMPOUNDS .4. EFFECT OF CATION BINDING ON THE PHOTOPHYSICAL PROPERTIES OF A COUMARIN LINKED TO MONOAZA-CROWN AND DIAZA-CROWN ETHERS [J].
BOURSON, J ;
POUGET, J ;
VALEUR, B .
JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (17) :4552-4557
[4]   A colorimetric ligand for mercuric ion [J].
Brummer, O ;
La Clair, JJ ;
Janda, KD .
ORGANIC LETTERS, 1999, 1 (03) :415-418
[5]   A new Hg2+-selective chromoionophore based on calix[4]arenediazacrown ether [J].
Choi, MJ ;
Kim, MY ;
Chang, SK .
CHEMICAL COMMUNICATIONS, 2001, (17) :1664-1665
[6]   Signaling recognition events with fluorescent sensors and switches [J].
de Silva, AP ;
Gunaratne, HQN ;
Gunnlaugsson, T ;
Huxley, AJM ;
McCoy, CP ;
Rademacher, JT ;
Rice, TE .
CHEMICAL REVIEWS, 1997, 97 (05) :1515-1566
[7]   Coupling selectivity with sensitivity in an integrated chemosensor framework:: Design of a Hg2+-responsive probe, operating above 500 nm [J].
Descalzo, AB ;
Martínez-Máñez, R ;
Radeglia, R ;
Rurack, K ;
Soto, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (12) :3418-3419
[8]  
DESVERGNE JP, 1996, NATO ASI SERIES C, V492
[9]   Synthetic receptors [J].
Hartley, JH ;
James, TD ;
Ward, CJ .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2000, (19) :3155-3184
[10]   Cyclic and open-chain aza-oxa ferrocene-functionalised derivatives as receptors for the selective electrochemical sensing of toxic heavy metal ions in aqueous environments [J].
Lloris, JM ;
Martínez-Máñez, R ;
Padilla-Tosta, ME ;
Pardo, T ;
Soto, J ;
Beer, PD ;
Cadman, J ;
Smith, DK .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (14) :2359-2369