A palladium complex containing a new C2-symmetric bidentate non-racemic oxalamidine ligand:: synthesis and catalytic properties

被引：21

作者：

Dupont, J

Ebeling, G

Delgado, MR

Consorti, CS

Burrow, R

Farrar, DH

Lough, AJ

机构：

[1] Univ Fed Rio Grande Sul, Lab Mol Catalysis, Inst Chem, BR-91501970 Porto Alegre, RS, Brazil

[2] Univ Fed Santa Maria, Dept Quim, BR-97105900 Santa Maria, RS, Brazil

[3] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 09期

关键词：

palladium; catalysis; amidines; hydro-arylation; asymmetric;

D O I：

10.1016/S1387-7003(01)00249-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Non-racemic (S, S, S, S)-(-)-2,2-bis-(4,5-diphenyl-1, 3-imidazoline) 1 has been prepared in good yields from the reaction of (S, S)(-)1,2-diphenylethylenediamine with diethyl oxalimidate. The reaction of 1 with sodium tetrachloropalladate yields [PdCl2(1)] complex 2, whose structure has been ascertained by means of X-ray diffraction analysis. Complex 2 catalyzes the hydro-arylation of norbornene in good catalytic activity but with poor enantioselectivity. (C) 2001 Elsevier Science BN. All rights reserved.

引用

页码：471 / 474

页数：4

共 19 条

[1] New highly active chiral phosphapalladacycle catalysts. First isolation and characterization of a Pd(IV) intermediate [J].