Photocurrent Generation from Thylakoid Membranes on Osmium-Redox-Polymer-Modified Electrodes

被引：62
作者：
Hamidi, Hassan [1 ,5 ]
Hasan, Kamrul [1 ]
Emek, Sinan Cem [1 ]
Dilgin, Yusuf [2 ]
Akerlund, Hans-Erik [1 ]
Albertsson, Per-Ake [1 ]
Leech, Donal [3 ,4 ]
Gorton, Lo [1 ]
机构：
[1] Lund Univ, Dept Analyt Chem Biochem & Struct Biol, SE-22100 Lund, Sweden
[2] Canakkale Onsekiz Mart Univ, Sci & Art Fac, Dept Chem, TR-17100 Canakkale, Turkey
[3] Natl Univ Ireland Galway, Sch Chem, Galway, Ireland
[4] Natl Univ Ireland Galway, Ryan Inst, Galway, Ireland
[5] Islamic Azad Univ, Dept Chem, Zanjan Branch, Zanjan, Iran
来源：
CHEMSUSCHEM | 2015年 / 8卷 / 06期
基金：
爱尔兰科学基金会; 瑞典研究理事会;
关键词：
electrodes; osmium; photosynthesis; redoxpolymers; thylakoid membranes; PHOTOSYSTEM-II; ELECTROCHEMICAL COMMUNICATION; PHOTOELECTROCHEMICAL COMMUNICATION; (BIO-)HYDROGEN PRODUCTION; RHODOBACTER-CAPSULATUS; CELLS; PHOTOSYNTHESIS; RECONSTITUTION; PHOTODAMAGE; CONVERSION;
D O I：
10.1002/cssc.201403200
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Thylakoid membranes (TMs) are uniquely suited for photosynthesis owing to their distinctive structure and composition. Substantial efforts have been directed towards use of isolated photosynthetic reaction centers (PRCs) for solar energy harvesting, however, few studies investigate the communication between whole TMs and electrode surfaces, due to their complex structure. Here we report on a promising approach to generate photosynthesis-derived bioelectricity upon illumination of TMs wired with an osmium-redox-polymer modified graphite electrode, and generate a photocurrent density of 42.4Acm(-2).
引用
收藏
页码：990 / 993
页数：4
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