The [4+3]-cycloaddition/quasi-Favorskii process. Synthesis of the carbocyclic core of tricycloclavulone

被引：52

作者：

Harmata, M ^{[1
]}

Wacharasindhu, S ^{[1
]}

机构：

[1] Univ Missouri, Dept Chem, Columbia, MO 65211 USA

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 13期

关键词：

D O I：

10.1021/ol050598l

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The [4 + 3]-cycloadduct derived from the reaction of 2,5-dibromocyclopentanone with cyclopentadiene was converted via a quasi-Favorskii rearrangement and ring-opening, ring-closing metathesis sequence to the carbocyclic core of the prostanoid tricycloclavulone.

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页码：2563 / 2565

页数：3

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