C-H activation of 2,4,6-triphenylphosphinine: unprecedented formation of cyclometalated [(P∧C)Ir(III)] and [(P∧C)Rh(III)] complexes

被引：29

作者：

Broeckx, Leen E. E. ^{[1
]}

Lutz, Martin ^{[2
]}

Vogt, Dieter ^{[1
]}

Mueller, Christian ^{[1
]}

机构：

[1] Eindhoven Univ Technol, Dept Chem & Chem Engn, Lab Homogeneous Catalysis & Coordinat Chem, NL-5600 MB Eindhoven, Netherlands

[2] Univ Utrecht, Bijvoet Ctr Biomol Res Crystal & Struct Chem, NL-3508 TC Utrecht, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 07期

关键词：

IRIDIUM COMPLEXES; ASTERISK-IR; LIGANDS; RH; REACTIVITY; CHEMISTRY; KINETICS; IMINES;

D O I：

10.1039/c0cc04660d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An unprecedented C-H activation of 2,4,6-triphenylphosphinine by Ir(III) and Rh(III) has been observed. Time-dependent P-31{H-1} NMR spectroscopy gave insight into the cyclometalation reaction and the corresponding coordination compounds were characterized by means of X-ray crystallography. In contrast, 2,4,6-triphenylpyridine does not show any ortho-metalation, demonstrating a remarkable difference in reactivity between these two structurally related aromatic heterocycles.

引用

收藏

页码：2003 / 2005

页数：3

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