ZnO/CuO/Al2O3 composites for chloroform detection

被引:14
作者
Nie, Mei-Xiang [1 ,2 ]
Li, Xiao-Zhou [1 ,2 ]
Liu, Shui-Ren [1 ,2 ]
Guo, Ying [1 ,2 ]
机构
[1] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
[2] Beijing Univ Chem Technol, Beijing Key Lab Environm Harmful Chem Anal, Beijing 100029, Peoples R China
基金
中国国家自然科学基金;
关键词
Metallic oxide; Composite; Gas sensing; Chloroform; GAS SENSOR; CHLORINATED HYDROCARBONS; CUO NANOSTRUCTURES; SENSING PROPERTIES;
D O I
10.1016/j.snb.2014.12.099
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this work, ZnO/CuO/Al2O3 composites were prepared via a simple coprecipitation and a hydrothermal method followed by a calcination process. The as-prepared composites were characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), Inductively Coupled Plasma (ICP), X-ray photoelectron spectroscopy (XPS) etc. Moreover, gas sensors based on ZnO/CuO/Al(2)O(3)were fabricated. It revealed that the sensor with certain metal ratio exhibited a fast and remarkable response to chloroform and was able to detect low concentration of chloroform down to 1 ppm in 20 s. The gas sensing mechanism was also discussed. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:211 / 217
页数:7
相关论文
共 32 条
  • [1] A rate equation approach to the gas sensitivity of thin film metal oxide materials
    Ahlers, S
    Müller, G
    Doll, T
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2005, 107 (02) : 587 - 599
  • [2] Theoretical and experimental study of the response of CuO gas sensor under ozone
    Bejaoui, A.
    Guerin, J.
    Zapien, J. A.
    Aguir, K.
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2014, 190 : 8 - 15
  • [3] Modeling of a p-type resistive gas sensor in the presence of a reducing gas
    Bejaoui, A.
    Guerin, J.
    Aguir, K.
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2013, 181 : 340 - 347
  • [4] Characterization of amorphous Pt/ZnO films grown on silicon(100) substrates by a photochemical metal organic deposition and their potential use as gas sensors
    Buono-Core, G. E.
    Klahn, A. H.
    Cabello, G.
    Lillo, L.
    [J]. POLYHEDRON, 2013, 62 : 1 - 6
  • [5] ZnO/ZnAl2O4 prepared by calcination of ZnAl layered double hydroxides for ethanol sensing
    Guan, Mei-Yu
    Xu, Dong-Mei
    Song, Yu-Fei
    Guo, Ying
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2013, 188 : 1148 - 1154
  • [6] A dynamic response model for the WO3-based ozone sensors
    Guerin, J.
    Bendahan, A.
    Aguir, K.
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2008, 128 (02) : 462 - 467
  • [7] Sensing properties of CuO-ZnO heterojunction gas sensors
    Hu, Y
    Zhou, XH
    Han, Q
    Cao, QX
    Huang, YX
    [J]. MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2003, 99 (1-3): : 41 - 43
  • [8] DETECTION OF CHLORINATED HYDROCARBONS VIA LASER-ATOMIZATION LASER-INDUCED FLUORESCENCE
    JEFFRIES, JB
    RAICHE, GA
    JUSINSKI, LE
    [J]. APPLIED PHYSICS B-PHOTOPHYSICS AND LASER CHEMISTRY, 1992, 55 (01): : 76 - 83
  • [9] Highly sensitive H2S gas sensors based on CuO-coated ZnSnO3 nanorods synthesized by thermal evaporation
    Jin, Changhyun
    Kim, Hyunsu
    An, Soyeon
    Lee, Chongmu
    [J]. CERAMICS INTERNATIONAL, 2012, 38 (07) : 5973 - 5978
  • [10] Kim J., 2012, J PHYS CHEM, V336