Antiferroelectric-ferroelectric phase boundary enhances polarization extension in rhombohedral Pb(Zr,Ti)O3

被引:19
作者
Ghosh, Anirban [1 ]
Damjanovic, Dragan [1 ]
机构
[1] Ecole Polytech Fed Lausanne, Swiss Fed Inst Technol Lausanne, Ceram Lab, CH-1015 Lausanne, Switzerland
关键词
SOLID-SOLUTION SYSTEMS; THERMODYNAMIC THEORY; SINGLE-CRYSTALS;
D O I
10.1063/1.3666233
中图分类号
O59 [应用物理学];
学科分类号
摘要
The main mechanism of properties enhancement in the morphotropic phase boundary region separating tetragonal and rhombohedral phases of Pb(Zr1-xTix)O-3 (PZT) is related to polarization rotation. It is shown here that in proximity of the morphotropic phase boundary separating antiferroelectric and rhombohedral phases (near x = 0.1) and at elevated temperatures the properties are dominated by polarization extension. These results may provide a guideline for developing alternative piezoelectric materials to PZT. (C) 2011 American Institute of Physics. [doi:10.1063/1.3666233]
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页数:3
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