Catalytic conversion of compounds representative of lignin-derived bio-oils: a reaction network for guaiacol, anisole, 4-methylanisole, and cyclohexanone conversion catalysed by Pt/γ-Al2O3

被引：156
作者：
Runnebaum, Ron C. [1 ]
Nimmanwudipong, Tarit [1 ]
Block, David E. [1 ,2 ]
Gates, Bruce C. [1 ]
机构：
[1] Univ Calif Davis, Dept Chem Engn & Mat Sci, Davis, CA 95616 USA
[2] Univ Calif Davis, Dept Viticulture & Enol, Davis, CA 95616 USA
来源：
CATALYSIS SCIENCE & TECHNOLOGY | 2012年 / 2卷 / 01期
关键词：
BIOMASS PYROLYSIS OIL; OXYGENATE COMPONENTS; HZSM-5; ZEOLITE; LIQUID FUELS; TRANSFORMATION; ALKANES;
D O I：
10.1039/c1cy00169h
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The conversion of compounds representative of lignin and lignin-derived bio-oils (guaiacol, anisole, 4-methylanisole, and cyclohexanone), catalysed by Pt/Al2O3 in the presence of H-2 at 573 K is described by a reaction network indicating a high selectivity for platinum-catalysed aromatic carbon-oxygen bond cleavage accompanied by acid-catalysed methyl group transfer reactions.
引用
收藏
页码：113 / 118
页数：6
相关论文
共 31 条
[1]   PRODUCTION OF HYDROCARBONS BY CATALYTIC UPGRADING OF A FAST PYROLYSIS BIO-OIL .1. CONVERSION OVER VARIOUS CATALYSTS [J].
ADJAYE, JD ;
BAKHSHI, NN .
FUEL PROCESSING TECHNOLOGY, 1995, 45 (03) :161-183
[2]   SPECIES RANK IN REACTION PATHWAYS - APPLICATION OF DELPLOT ANALYSIS [J].
BHORE, NA ;
KLEIN, MT ;
BISCHOFF, KB .
CHEMICAL ENGINEERING SCIENCE, 1990, 45 (08) :2109-2116
[3]   THE DELPLOT TECHNIQUE - A NEW METHOD FOR REACTION PATHWAY ANALYSIS [J].
BHORE, NA ;
KLEIN, MT ;
BISCHOFF, KB .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1990, 29 (02) :313-316
[4]   REACTIONS OF PHENOLIC-COMPOUNDS OVER HZSM-5 [J].
CHANTAL, PD ;
KALIAGUINE, S ;
GRANDMAISON, JL .
APPLIED CATALYSIS, 1985, 18 (01) :133-145
[5]   Overview of applications of biomass fast pyrolysis oil [J].
Czernik, S ;
Bridgwater, AV .
ENERGY & FUELS, 2004, 18 (02) :590-598
[6]   Catalytic Hydroprocessing of Biomass Fast Pyrolysis Bio-oil to Produce Hydrocarbon Products [J].
Elliott, Douglas C. ;
Hart, Todd R. ;
Neuenschwander, Gary G. ;
Rotness, Leslie J. ;
Zacher, Alan H. .
ENVIRONMENTAL PROGRESS & SUSTAINABLE ENERGY, 2009, 28 (03) :441-449
[7]   Catalytic Hydroprocessing of Chemical Models for Bio-oil [J].
Elliott, Douglas C. ;
Hart, Todd R. .
ENERGY & FUELS, 2009, 23 (1-2) :631-637
[8]   Catalytic routes from renewables to fine chemicals [J].
Gallezot, Pierre .
CATALYSIS TODAY, 2007, 121 (1-2) :76-91
[9]   Transformation of oxygenate components of biomass pyrolysis oil on a HZSM-5 zeolite. H. Aldehydes, ketones, and acids [J].
Gayubo, AG ;
Aguayo, AT ;
Atutxa, A ;
Aguado, R ;
Olazar, M ;
Bilbao, J .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2004, 43 (11) :2619-2626
[10]   Transformation of oxygenate components of biomass pyrolysis oil on a HZSM-5 zeolite. I. Alcohols and phenols [J].
Gayubo, AG ;
Aguayo, AT ;
Atutxa, A ;
Aguado, R ;
Bilbao, J .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2004, 43 (11) :2610-2618
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