Analysis of organochlorine pesticides in surface water of the Songhua River using magnetoliposomes as adsorbents coupled with GC-MS/MS detection

A simple and effective method based on magnetic separation has been developed for the extraction of organo-chlorine pesticides (OCPs) from river water samples using magnetoliposomes as adsorbents. This method avoided the time-consuming column passing process of loading large volume samples in traditional SPE through the rapid isolation of magnetoliposomes with an adscititious magnet. Lipid bilayers formed on the surface of Fe3O4 showed great adsorptive tendency towards analytes through hydrophobic interactions, and zwitterions headgroups endowed the outer surface of magnetoliposomes with hydrophilicity to improve the dispersing property of adsorbents in the sample matrix. The target analytes were detected by gas chromatography-tandem mass spectrometry, and the limits of detection obtained are in the range of 0.04-0.35 ng L-1. The relative standard deviations of intra- and inter-day are in the range of 2-5% and 4-7%, respectively. The proposed method was employed for analysis of six OCPs in the surface water samples from two cities along the Songhua River in different seasons. Compared with the traditional methods, the proposed method could reduce the consumption of the organic solvent and shorten the sample preparation time. (c) 2017 Published by Elsevier B.V.