High temperature heat capacity of PuPO4 monazite-analogue

被引：13

作者：

Benes, Ondrej ^{[1
]}

Popa, Karin ^{[2
]}

Reuscher, Vivien ^{[1
,3
]}

Zappia, Alessandro ^{[1
]}

Staicu, Dragos ^{[1
]}

Konings, Rudy J. M. ^{[1
]}

机构：

[1] European Commiss, Joint Res Ctr, Inst Transuranium Elements, D-76125 Karlsruhe, Germany

[2] Alexandru Ioan Cuza Univ, Dept Chem, Iasi 700506, Romania

[3] Heidelberg Univ, Inst Phys Chem, D-69120 Heidelberg, Germany

来源：

JOURNAL OF NUCLEAR MATERIALS | 2011年 / 418卷 / 1-3期

关键词：

PLUTONIUM; PHOSPHATES; CERAMICS; BEHAVIOR;

D O I：

10.1016/j.jnucmat.2011.06.037

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The enthalpy increments of PuPO4 have been measured using drop calorimetry in the temperature range from 530 K to 1386 K. The heat capacity was derived from the obtained data and compared with heat capacity data obtained directly from differential scanning calorimeter measured in this study from 400 K to 1400 K. The recommended heat capacity of PuPO4 was determined based on both techniques as: C-p(0) (J K-1 mol(-1)) = 126.600 + 32.999 x 10(-3) (T/K) - 1.9503 x 10(6) (T/K)(-2). (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：182 / 185

页数：4

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