Experimental investigation and thermodynamic modeling of the Mg-Si-Zn system

被引:9
作者
Wang, Man [1 ]
Wang, Peisheng [1 ]
Liu, Shuhong [1 ,2 ]
Du, Yong [1 ,2 ]
Xu, Honghui [1 ,2 ]
Zhang, Wenqing [3 ]
机构
[1] Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China
[2] Cent S Univ, Sci Ctr Phase Diagram & Mat Design & Mfg, Changsha 410083, Hunan, Peoples R China
[3] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
来源
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY | 2011年 / 35卷 / 02期
基金
中国国家自然科学基金;
关键词
Mg-Si-Zn system; Isothermal section; Thermodynamic modeling; XRD; SEM/EDX; KEY EXPERIMENTS; TEMPERATURE; MAGNESIUM; ALLOYS;
D O I
10.1016/j.calphad.2011.01.003
中图分类号
O414.1 [热力学];
学科分类号
摘要
The isothermal section at 327 degrees C for the Mg-Si-Zn system has been determined by means of X-ray diffraction (XRD) and scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM/EDX). No ternary compound has been observed in this work. Five three-phase regions, (Zn) + (Si) + Mg(2)Zn(11). Mg(2)Zn(11) + MgZn(2) + Mg(2)Si, Mg(2)Zn(3) + MgZn(2) + Mg(2)Si, Mg(51)Zn(20) + MgZn + Mg(2)Si, and Mg(51)Zn(20) + Mg(2)Si + (Mg), have been determined. No appreciable ternary solubility has been detected. An optimal set of thermodynamic parameters for the Mg-Si-Zn system has been obtained by considering the experimental data from both the present work and the literature. The agreement between calculation and experiment is reasonable. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:183 / 190
页数:8
相关论文
共 20 条
[1]  
AGARWAL R, 1992, Z METALLKD, V83, P216
[2]  
Bollenrath F., 1946, Metallfroschung, V1, P116
[3]   Experimental investigation and thermodynamic modeling of the ternary Al-Cu-Fe system [J].
Chen, Hai-Lin ;
Du, Yong ;
Xu, Honghui ;
Xiong, Wei .
JOURNAL OF MATERIALS RESEARCH, 2009, 24 (10) :3154-3164
[4]   SGTE DATA FOR PURE ELEMENTS [J].
DINSDALE, AT .
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 1991, 15 (04) :317-425
[5]   THERMODYNAMIC MODELING OF THE AL-K SYSTEM [J].
Du, Y. ;
Yuan, X. ;
Sun, W. ;
Hu, B. .
JOURNAL OF MINING AND METALLURGY SECTION B-METALLURGY, 2009, 45 (01) :89-93
[6]   A thermodynamic description of the Al-Fe-Si system over the whole composition and temperature ranges via a hybrid approach of CALPHAD and key experiments [J].
Du, Yong ;
Schuster, Julius Clemens ;
Liu, Zi-Kui ;
Hu, Rongxiang ;
Nash, Philip ;
Sun, Weihua ;
Zhang, Weiwei ;
Wang, Jiong ;
Zhang, Lijun ;
Tang, Chengying ;
Zhu, Zhijun ;
Liu, Shuhong ;
Ouyang, Yifang ;
Zhang, Wenqing ;
Krendelsberger, Nataliya .
INTERMETALLICS, 2008, 16 (04) :554-570
[7]  
Elchardus E, 1935, CR HEBD ACAD SCI, V200, P1938
[8]  
Elchardus E., 1933, C. R. Acad. Sci. Paris, V197, P1125
[9]   Measurement of the isothermal sections at 700 and 427°C in the Al-Mg-Ni system [J].
He, Cuiyun ;
Du, Yong ;
Chen, Hai-Lin ;
Ouyang, Hongwu .
INTERNATIONAL JOURNAL OF MATERIALS RESEARCH, 2008, 99 (08) :907-911
[10]   Thermodynamic modeling of the Cu-Mn system supported by key experiments [J].
He, Cuiyun ;
Du, Yong ;
Chen, Hai-Lin ;
Liu, Shuhong ;
Xu, Honghui ;
Ouyang, Wang ;
Liu, Zi-Kui .
JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 457 (1-2) :233-238