Surface termination and Schottky-barrier formation of In4Se3(001)

被引:17
作者
Dhingra, Archit [1 ]
Galiy, Pavlo, V [2 ]
Wang, Lu [3 ]
Vorobeva, Nataliia S. [4 ]
Lipatov, Alexey [4 ]
Torres, Angel [4 ]
Nenchuk, Taras M. [2 ]
Gilbert, Simeon J. [1 ]
Sinitskii, Alexander [4 ]
Yost, Andrew J. [5 ]
Mei, Wai-Ning [6 ]
Fukutani, Keisuke [1 ,8 ]
Chen, Jia-Shiang [7 ]
Dowben, Peter A. [1 ]
机构
[1] Univ Nebraska, Dept Phys & Astron, Jorgenson Hall,855 North 16th St, Lincoln, NE 68588 USA
[2] Ivan Franko Lviv Natl Univ, Elect Dept, Lvov, Ukraine
[3] Univ Sci & Technol China, CAS Key Lab Mat Energy Convers, Hefei, Peoples R China
[4] Univ Nebraska, Dept Chem, Lincoln, NE 68588 USA
[5] Oklahoma State Univ, Dept Phys, Stillwater, OK 74078 USA
[6] Univ Nebraska, Dept Phys, Omaha, NE 68182 USA
[7] Brookhaven Natl Lab, Ctr Funct Nanomat, Upton, NY 11973 USA
[8] Inst Basic Sci IBS, Ctr Artificial Low Dimens Elect Syst, Pohang 37673, South Korea
基金
美国国家科学基金会;
关键词
quasi-1D trichalcogenide; surface termination; surface-to-bulk core level shift; Schottky barrier; In4Se3; HIGH THERMOELECTRIC PERFORMANCE; GRAPHENE NANORIBBONS; PHOTOELECTRON DIFFRACTION; CRYSTAL-STRUCTURE; OHMIC CONTACTS; SEMICONDUCTOR; TRANSITION; TRANSPORT; STATES; ATOMS;
D O I
10.1088/1361-6641/ab7e45
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
The surface termination of In4Se3(001) and the interface of this layered trichalcogenide, with Au, was examined using x-ray photoemission spectroscopy. Low energy electron diffraction indicates that the surface is highly crystalline, but suggests an absence of C-2v mirror plane symmetry. The surface termination of the In4Se3(001) is found, by angle-resolved x-ray photoemission spectroscopy, to be In, which is consistent with the observed Schottky barrier formation found with this n-type semiconductor. Transistor measurements confirm earlier results from photoemission, suggesting that In4Se3(001) is an n-type semiconductor, so that Schottky barrier formation with a large work function metal, such as Au, is expected. The measured low carrier mobilities could be the result of the contacts and would be consistent with Schottky barrier formation.
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页数:9
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