Chiral heterocyclic ligands. XVII. Pyridine-amino acid hybrid ligands: synthesis and crystal structures of metal complexes of a chelating ligand derived from L-alanine

被引:2
作者
Lewis, William [1 ]
Steel, Peter J. [1 ]
机构
[1] Univ Canterbury, Dept Chem, Coll Sci, Christchurch 1, New Zealand
关键词
Copper; Silver; N Ligands; Chiral ligands; SILVER COORDINATION POLYMERS; DESIGN;
D O I
10.1080/00958972.2010.544302
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A hybrid L-alanine-picolinamide is shown to act as an N,O-chelating ligand upon reaction with copper(II) nitrate and silver(I) perchlorate. X-ray crystal structures reveal that both these chiral complexes further assemble into 1-D polymeric chains through hydrogen bonding associations.
引用
收藏
页码:115 / 121
页数:7
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