Kinetics and mechanism of metal ion catalysis: Part II. Oxidation of PhCHO by osmium(VIII) continuously regenerated by hexacyanoferrate(III) ions

被引：2

作者：

Mehta, SPS ^{[1
]}

Tewary, G ^{[1
]}

机构：

[1] Kumaun Univ, Dept Chem, Naini Tal 263002, India

来源：

TRANSITION METAL CHEMISTRY | 2001年 / 26卷 / 03期

关键词：

Oxidation; Physical Chemistry; Hydrate; Inorganic Chemistry; Catalysis;

D O I：

10.1023/A:1007184621336

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The kinetics of the oxidation of PhCHO by Os-VIII has been studied in 0.01-0.05 M [OH-] range. Fe(CN)(3)-(6) was used to regenerate Os-VIII. The very low solubility of PhCHO in H2O restricted the study to the 0.0024-0.0036 M [PhCHO] range. A mechanism involving the PhCHO hydrate has been proposed.

引用

页码：290 / 294

页数：5

共 15 条

[1]

AZIZ F, 1964, TALANTA, V11, P889

[2] METAL-ION CATALYSIS IN SOME REACTIONS OF HEXACYANOFERRATE(III) .3. OXIDATION OF HYDROXYLAMINE [J].