Studies on the Uptake of Uranium(VI) Ions on Polyacrylamidoxime Resins Synthesized by Free Radical Polymerization with Different Crosslinking Ratios and Pore Solvents

被引：17

作者：

Abdel-Rahman, Adel A-H ^{[1
]}

Atta, Ayman M. ^{[2
]}

El Aassy, Ibrahim E. ^{[3
]}

Ahmed, Fadia Y. ^{[3
]}

Hamza, Mohammed F. ^{[3
]}

机构：

[1] Menoufiya Univ, Fac Sci, Dept Chem, Shibin Al Kawm, Egypt

[2] Egyptian Petr Res Inst, Nasr City, Cairo, Egypt

[3] Nucl Mat Author, Cairo, Egypt

来源：

JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY | 2011年 / 32卷 / 02期

关键词：

Crosslinking ratio; polyacrylamidoxime; pore solvent; uranium; HYDROXYLAMINE FUNCTIONAL-GROUPS; INDUCED GRAFT-COPOLYMERIZATION; CHELATING RESIN; METAL-IONS; AMIDOXIME; RECOVERY; ADSORPTION; SEAWATER; PRECONCENTRATION; ACRYLONITRILE;

D O I：

10.1080/01932691003656946

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Uptake of uranyl ions on polyacrylamidoxime resins synthesized from polymerization of acrylonitrile, and divinylbenzene as crosslinking agent in the presence of different diluents, then conversion of polyacrylonitrile to polyacrylamidoxime by hydroxylamine in basic media were investigated. FTIR on base polymer, functional resins, resins loaded with uranyl ions and that after elution were investigated. The effect of pore solvents on the morphologies of the prepared resins were examined by scanning electron microscope. Loading of uranyl ions performed with respect effects of pH, time of loading, and ratio of crosslinker. Elution of adsorbed ions carried out with different eluent and elution efficiency were determined. Regeneration of resins performed after six cycles and regeneration efficiency were determined.

引用

页码：224 / 234

页数：11

共 42 条

[1] [Anonymous], 2000, SOLID PHASE EXTRACTI
[2] [Anonymous], 2007, AMBIO
[3] [Anonymous], 2005, SITU REMEDIATION ENG
[4] [Anonymous], 2003, ENVIRON SCI TECHNOL, DOI DOI 10.1021/es0210042
[5] DEVELOPMENT OF SORBERS FOR THE RECOVERY OF URANIUM FROM SEAWATER .2. THE ACCUMULATION OF URANIUM FROM SEAWATER BY RESINS CONTAINING AMIDOXIME AND IMIDOXIME FUNCTIONAL-GROUPS
ASTHEIMER, L
SCHENK, HJ
WITTE, EG
SCHWOCHAU, K
[J]. SEPARATION SCIENCE AND TECHNOLOGY, 1983, 18 (04) : 307 - 339
[6] A novel multi-element coprecipitation technique for separation and enrichment of metal ions in environmental samples
Aydin, Funda Armagan
Soylak, Mustafa
[J]. TALANTA, 2007, 73 (01) : 134 - 141
[7] An alternative to interpenetration whereby nets with large windows may achieve satisfactory space filling
Batten, SR
Hoskins, BF
Moubaraki, B
Murray, KS
Robson, R
[J]. CHEMICAL COMMUNICATIONS, 2000, (13) : 1095 - 1096
[8] Becker T., 2000, Reactive and Functional Polymers, V44, P289, DOI DOI 10.1016/S1381-5148(99)00104-2
[9] Synthesis and applications of chitosan mercaptanes as heavy metal retention agent
Cárdenas, G
Orlando, P
Edelio, T
[J]. INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2001, 28 (02) : 167 - 174
[10] ONLINE PRECONCENTRATION AND DETERMINATION OF TRACE-ELEMENTS BY FLOW-INJECTION INDUCTIVELY COUPLED PLASMA ATOMIC EMISSION-SPECTROMETRY
CAROLI, S
ALIMONTI, A
PETRUCCI, F
HORVATH, Z
[J]. ANALYTICA CHIMICA ACTA, 1991, 248 (01) : 241 - 249

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