Metal-catalyzed C-H activation for polymer synthesis and functionalization

被引：65

作者：

Yang, Yang ^{[1
]}

Nishiura, Masayoshi ^{[1
,2
]}

Wang, Haobing ^{[1
]}

Hou, Zhaomin ^{[1
,2
]}

机构：

[1] RIKEN Ctr Sustainable Resource Sci, Adv Catalysis Res Grp, 2-1 Hirosawa, Wako, Saitama 3510198, Japan

[2] RIKEN Cluster Pioneering Res, Organometall Chem Lab, 2-1 Hirosawa, Wako, Saitama 3510198, Japan

来源：

COORDINATION CHEMISTRY REVIEWS | 2018年 / 376卷

关键词：

C-H activation; Polymer synthesis; Transition metal; Catalysis; DIRECT ARYLATION POLYMERIZATION; STEP-GROWTH COPOLYMERIZATION; DIRECT (HETERO)ARYLATION POLYMERIZATION; PI-CONJUGATED POLYMERS; RIGID LADDER POLYMERS; MIXED-LIGAND APPROACH; RARE-EARTH CATALYSTS; HEAD-TO-TAIL; CHAIN-TRANSFER; COUPLING POLYMERIZATION;

D O I：

10.1016/j.ccr.2018.08.017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Transition-metal-catalyzed C-H bond activation has attracted substantial interest in recent years as an efficient, step-economic, and environmentally benign pathway for the synthesis of functional polymers. The polymerization reaction may proceed through C-H/C-X cross-coupling, oxidative C-H/C-H coupling, and C-H addition to unsaturated C-C bonds. C-H activation may also serve as a chain transfer reaction for olefin polymerization and polymer post-functionalization. This review summarizes recent advances in this area. (C) 2018 Elsevier B.V. All rights reserved.

引用

页码：506 / 532

页数：27

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