The electrochemical reduction of benzaldehyde and acetophenone on a platinum electrode chemically modified with tetraphenyl porphyrine

被引:0
作者
Lete, C
Totir, ND
Giorza, C
Preda, L
机构
[1] Acad Romane, Inst Chim Fiz IG Murgulescu, Bucharest 060021, Romania
[2] Liceul Arte Plast Corneliu Baba, Bistrita 4201701, Romania
来源
REVISTA DE CHIMIE | 2003年 / 54卷 / 05期
关键词
benzaldehyde; platinum electrode; porphyrins derivatives;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The electrochemical reduction of acetophenone and benzaldehyde on modified,platinum electrode with some porphyrins derivatives has been achieved. Electrochemical behavior of acetophenone and benzaldehyde was studied by cyclic voltammetry. The electrocatalytic activity for derivative porphyrins has been established. Experimental results regarding the electroreduction of acetophenone on platinum modified with porphyrine derivatives indicates that the reaction between dianion and organic substrate is the rate determining step.
引用
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页码:411 / 413
页数:3
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