Facile and efficient hydrolysis of organic halides, epoxides, and esters with water catalyzed by ferric sulfate in a PEG1000-DAIL[BF4]/toluene temperature-dependent biphasic system

被引：26

作者：

Hu, Yu Lin ^{[1
]}

Jiang, Hui ^{[1
]}

Zhu, Jie ^{[1
]}

Lu, Ming ^{[1
]}

机构：

[1] Nanjing Univ Sci & Technol, Coll Chem Engn, Nanjing 210094, Peoples R China

来源：

NEW JOURNAL OF CHEMISTRY | 2011年 / 35卷 / 02期

关键词：

IONIC LIQUIDS; SOLVENT;

D O I：

10.1039/c0nj00454e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient and environmentally friendly procedure for the hydrolysis of organic halides, epoxides, and esters with water catalyzed by ferric sulfate in a PEG(1000)-DAIL[BF4]/toluene temperature-dependent biphasic system has been developed. The product can be easily isolated by a simple decantation, and the catalytic system can be recycled and reused without loss of catalytic activity.

引用

页码：292 / 298

页数：7

共 22 条

[1] Hydrolysis of alkenyl esters and ethers catalyzed by metal complexes [J].

Aoyama, H ;

Tokunaga, M ;

Hiraiwa, S ;

Shirogane, Y ;

Obora, Y ;

Tsuji, Y .

ORGANIC LETTERS, 2004, 6 (04) :509-512

[2]

Base C.F., 1976, The hydrolysis of cations

[3]

BLAY G, 1989, SYNTHESIS-STUTTGART, P438

[4]

Bunton C.A., 1987, Adv. Phys. Org. Chem, V22, P213, DOI [10.1016/S0065-3160(08)60169-0, DOI 10.1016/S0065-3160(08)60169-0]

[5] MICROWAVE-ASSISTED ORGANIC-REACTIONS [J].

CADDICK, S .

TETRAHEDRON, 1995, 51 (38) :10403-10432

[6]

Carey F.A., 1990, Advanced Organic Chemistry Part A: Structure and Mechanisms, V3

[7] Novel bronsted acidic ionic liquids and their use as dual solvent-catalysts [J].

Cole, AC ;

Jensen, JL ;

Ntai, I ;

Tran, KLT ;

Weaver, KJ ;

Forbes, DC ;

Davis, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (21) :5962-5963

[8] The distillation and volatility of ionic liquids [J].

Earle, MJ ;

Esperança, JMSS ;

Gilea, MA ;

Lopes, JNC ;

Rebelo, LPN ;

Magee, JW ;

Seddon, KR ;

Widegren, JA .

NATURE, 2006, 439 (7078) :831-834

[9] Functionalised ionic liquids: synthesis of ionic liquids with tethered basic groups and their use in Heck and Knoevenagel reactions [J].

Forsyth, Stewart A. ;

Froehlich, Ute ;

Goodrich, Peter ;

Gunaratne, H. Q. Nimal ;

Hardacre, Christopher ;

McKeown, Angela ;

Seddon, Kenneth R. .

NEW JOURNAL OF CHEMISTRY, 2010, 34 (04) :723-731

[10] Ionic liquids in electrochemical devices and processes: managing interfacial Electrochemistry [J].

Macfarlane, Douglas R. ;

Forsyth, Maria ;

Howlett, Patrick C. ;

Pringle, Jennifer M. ;

Sun, Jiazeng ;

Annat, Gary ;

Neil, Wayne ;

Izgorodina, Ekaterina I. .

ACCOUNTS OF CHEMICAL RESEARCH, 2007, 40 (11) :1165-1173

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