Self-Supported Transition-Metal-Based Electrocatalysts for Hydrogen and Oxygen Evolution

被引：1560

作者：

Sun, Hongming ^{[1
]}

Yan, Zhenhua ^{[1
]}

Liu, Fangming ^{[1
]}

Xu, Wence ^{[1
]}

Cheng, Fangyi ^{[1
]}

Chen, Jun ^{[1
]}

机构：

[1] Nankai Univ, Key Lab Adv Energy Mat Chem, Renewable Energy Convers & Storage Ctr, Minist Educ,Coll Chem, Tianjin 300071, Peoples R China

来源：

ADVANCED MATERIALS | 2020年 / 32卷 / 03期

关键词：

electrocatalysis; hydrogen evolution; oxygen evolution; self-supported electrodes; transition metals; DOUBLE HYDROXIDE NANOSHEETS; PT-LIKE ACTIVITY; BIFUNCTIONAL ELECTROCATALYST; NANOWIRE ARRAYS; NICKEL FOAM; REDUCTION/EVOLUTION REACTION; CATALYTIC-ACTIVITY; MOS2; NANOSHEETS; CARBON CLOTH; EFFICIENT;

D O I：

10.1002/adma.201806326

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrochemical water splitting is a promising technology for sustainable conversion, storage, and transport of hydrogen energy. Searching for earth-abundant hydrogen/oxygen evolution reaction (HER/OER) electrocatalysts with high activity and durability to replace noble-metal-based catalysts plays paramount importance in the scalable application of water electrolysis. A freestanding electrode architecture is highly attractive as compared to the conventional coated powdery form because of enhanced kinetics and stability. Herein, recent progress in developing transition-metal-based HER/OER electrocatalytic materials is reviewed with selected examples of chalcogenides, phosphides, carbides, nitrides, alloys, phosphates, oxides, hydroxides, and oxyhydroxides. Focusing on self-supported electrodes, the latest advances in their structural design, controllable synthesis, mechanistic understanding, and strategies for performance enhancement are presented. Remaining challenges and future perspectives for the further development of self-supported electrocatalysts are also discussed.

引用

页数：18

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