Synthesis and structural characterization of phosphinate coordination polymers with tin(IV) and copper(II)

被引:14
作者
Gholivand, Khodayar [1 ]
Fallah, Nasrin [2 ]
Valmoozi, Ali Asghar Ebrahimi [1 ]
Gholami, Akram [1 ]
Dusek, Michal [3 ]
Eigner, Vaclav [3 ]
Pooyan, Mahsa [1 ]
Mohammadpanah, Fahimeh [1 ]
机构
[1] Tarbiat Modares Univ, Fac Basic Sci, Dept Chem, Tehran, Iran
[2] Islamic Azad Univ, Dept Chem, Sci & Res Branch, Tehran, Iran
[3] ASCR, Inst Phys, Na Slovance 2, Prague 18221 8, Czech Republic
关键词
Coordination polymer; Phosphinate; Tin(IV); Copper(II); Intermolecular interactions; Hirshfeld surface analysis; CRYSTAL-STRUCTURE; X-RAY; LIGANDS; ADDUCTS; DENSITY; ACID; BOND;
D O I
10.1016/j.molstruc.2019.127369
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work, we report the synthesis and X-ray characterization of diphenylphosphinic acid (L) (redetermination at 100 K), and its two polymeric phosphinate complexes; [(C6H5)(2)P(O)OSn(C6H5)(3)](n) (C1) and [Cu(O2PPh2)(2)](n) (C2), resulted from the bidentate coordinatioan of L. Sn(IV) centers in C1 are five-coordinate in a distorted trigonal bipyramidal geometry. One dimensional coordination chains of C2 are made by double-bridging ligands between the copper atoms, surrounded with four P-O in a square planar polyhedron. Structural characterization of the complexes revealed that M - O bonds are responsible for the assembly of the primary structural motifs in both the complexes while C-H center dot center dot center dot pi and H center dot center dot center dot H interactions are effective in organizing these molecules into extended 3D architectures. The quantitative mapping of interactions was also analyzed using Hirshfeld surface analysis. With respect to the (PNMR)-P-31 spectra, there are probably fast transformations in the solution and different types of coordinated and dissociated species are in balance, consistent with the optimized structures in the solvent and gas phases. (C) 2019 Elsevier B.V. All rights reserved.
引用
收藏
页数:9
相关论文
共 25 条
  • [1] Synthesis Characterization and Biological Activities of Coordination Compounds of 4-Hydroxy-3-nitro-2H-chromen-2-one and Its Aminoethanoic Acid and Pyrrolidine-2-carboxylic Acid Mixed Ligand Complexes
    Aiyelabola, Temitayo
    Akinkunmi, Ezekiel
    Obuotor, Efere
    Olawuni, Idowu
    Isabirye, David
    Jordaan, Johan
    [J]. BIOINORGANIC CHEMISTRY AND APPLICATIONS, 2017, 2017
  • [2] TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS
    ALLEN, FH
    KENNARD, O
    WATSON, DG
    BRAMMER, L
    ORPEN, AG
    TAYLOR, R
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12): : S1 - S19
  • [3] [Anonymous], APEX2 SOFTW PACK
  • [4] New dibutyltin(IV) ladders: Syntheses, structures and, optimization and evaluation of cytotoxic potential employing A375 (melanoma) and HCT116 (colon carcinoma) cell lines in vitro
    Baul, Tushar S. Basu
    Dutta, Dhrubajyoti
    Duthie, Andrew
    Guchhait, Nikhil
    Rocha, Bruno G. M.
    Guedes da Silva, M. Fatima C.
    Mokhamatam, Raveendra B.
    Raviprakash, Nune
    Manna, Sunil K.
    [J]. JOURNAL OF INORGANIC BIOCHEMISTRY, 2017, 166 : 34 - 48
  • [5] DENSITY-FUNCTIONAL THERMOCHEMISTRY .3. THE ROLE OF EXACT EXCHANGE
    BECKE, AD
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (07) : 5648 - 5652
  • [6] Industrial applications of metal-organic frameworks
    Czaja, Alexander U.
    Trukhan, Natalia
    Mueller, Ulrich
    [J]. CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) : 1284 - 1293
  • [7] Hydrogen storage in microporous metal-organic frameworks with exposed metal sites
    Dinca, Mircea
    Long, Jeffrey R.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (36) : 6766 - 6779
  • [8] CRYSTAL-STRUCTURE OF DIPHENYLPHOSPHINIC ACID
    FENSKE, D
    MATTES, R
    LONS, J
    TEBBE, KF
    [J]. CHEMISCHE BERICHTE-RECUEIL, 1973, 106 (04): : 1139 - 1144
  • [9] Frisch M. J., [No title captured]
  • [10] The Chemistry and Applications of Metal-Organic Frameworks
    Furukawa, Hiroyasu
    Cordova, Kyle E.
    O'Keeffe, Michael
    Yaghi, Omar M.
    [J]. SCIENCE, 2013, 341 (6149) : 974 - +