Congested C2-symmetric aryliodanes based on an anti-dimethanoanthracene backbone

被引：19
作者：
Murray, Stephen J. [1 ]
Mueller-Bunz, Helge [1 ]
Ibrahim, Hasim [1 ]
机构：
[1] Natl Univ Ireland Univ Coll Dublin, Ctr Synth & Chem Biol, Sch Chem & Chem Biol, Dublin 4, Ireland
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 50期
基金：
爱尔兰科学基金会;
关键词：
ONE-POT SYNTHESIS; DIARYLIODONIUM SALTS; POTASSIUM PEROXODISULFATE; IODINE; IODOARENES; (DIACETOXYIODO)ARENES; DEAROMATIZATION; REAGENTS; OXIDANT; ARENES;
D O I：
10.1039/c2cc32280c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A family of congested aryliodanes based on an anti-dimethanoanthracene backbone has been synthesised and two diaryliodonium salts and the iodyl derivative characterised by X-ray analysis. The latter shows a rare water coordination to the iodine(V) centre in the solid state. Applications of these reagents in functional group transfer reactions are reported.
引用
收藏
页码：6268 / 6270
页数：3
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