Manganese-Mediated Homolytic Aromatic Substitution with Phosphinylidenes

被引:17
作者
Berger, Olivier [1 ]
Montchamp, Jean-Luc [1 ]
机构
[1] Texas Christian Univ, Dept Chem & Biochem, TCU Box 298860, Ft Worth, TX 76133 USA
基金
美国国家科学基金会;
关键词
homolytic aromatic substitution; phosphonate; phosphinate; manganese; arylation; CROSS-COUPLING REACTIONS; CARBON BOND FORMATION; REGIOSELECTIVE PHOSPHONATION; DIOXIDE OXIDATION; ACETATE; PHOSPHORYLATION; HETEROARYL; ARYL; PHOSPHONYLATION; TRANSFORMATION;
D O I
10.1002/tcr.201700021
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Carbon-phosphorus (C-P) bond-forming reactions via homolytic aromatic substitution (HAS) of non-functionalized substrates with phosphinylidene P(O)H compounds is becoming a useful synthetic tool for the preparation of aryl and heteroaryl phosphonates, phosphinates, and phosphine oxides. This review specifically covers recent work using manganese-mediated free radical processes. Several research groups employ expensive Mn(OAc)(3), whereas our own contributions focus on the novel and inexpensive Mn(OAc)(2)/MnO2 system.
引用
收藏
页码:1203 / 1212
页数:10
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