Manganese-Mediated Homolytic Aromatic Substitution with Phosphinylidenes

被引：17

作者：

Berger, Olivier ^{[1
]}

Montchamp, Jean-Luc ^{[1
]}

机构：

[1] Texas Christian Univ, Dept Chem & Biochem, TCU Box 298860, Ft Worth, TX 76133 USA

来源：

CHEMICAL RECORD | 2017年 / 17卷 / 12期

基金：

美国国家科学基金会;

关键词：

homolytic aromatic substitution; phosphonate; phosphinate; manganese; arylation; CROSS-COUPLING REACTIONS; CARBON BOND FORMATION; REGIOSELECTIVE PHOSPHONATION; DIOXIDE OXIDATION; ACETATE; PHOSPHORYLATION; HETEROARYL; ARYL; PHOSPHONYLATION; TRANSFORMATION;

D O I：

10.1002/tcr.201700021

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbon-phosphorus (C-P) bond-forming reactions via homolytic aromatic substitution (HAS) of non-functionalized substrates with phosphinylidene P(O)H compounds is becoming a useful synthetic tool for the preparation of aryl and heteroaryl phosphonates, phosphinates, and phosphine oxides. This review specifically covers recent work using manganese-mediated free radical processes. Several research groups employ expensive Mn(OAc)(3), whereas our own contributions focus on the novel and inexpensive Mn(OAc)(2)/MnO2 system.

引用

页码：1203 / 1212

页数：10

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