An electrochemical study of a PEM stack for water electrolysis

被引:121
|
作者
Siracusano, S. [1 ]
Baglio, V. [1 ]
Briguglio, N. [1 ]
Brunaccini, G. [1 ]
Di Blasi, A. [1 ]
Stassi, A. [1 ]
Ornelas, R. [2 ]
Trifoni, E. [2 ]
Antonucci, V. [1 ]
Arico, A. S. [1 ]
机构
[1] CNR ITAE, I-98126 Messina, Italy
[2] Tozzi Renewable Energy SpA, I-48010 Mezzano, RA, Italy
关键词
PEM electrolyzer; Stack; Water electrolysis; Hydrogen production; Efficiency; OXYGEN EVOLUTION REACTION; HYDROGEN; ELECTROCATALYSIS; PERFORMANCE; ANODE; CELL; OPERATION;
D O I
10.1016/j.ijhydene.2011.06.019
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The electrochemical properties of a proton exchange membrane (PEM) stack electrolyzer (9 cells of 100 cm(2) geometrical area) were investigated at different temperatures. An amount of H-2 of similar to 2701h(-1) was produced at 60 A (600 mA cm(-2)) and 70 degrees C under 876 W of applied electrical power. The corresponding specific energy consumed in the process was 3.24 Wh.1(-1)H(2). The Faradic and electrical efficiencies were determined. Overall stack efficiencies of 73% and 85%, at 60 A and 70 degrees C, with respect to the low and high heating value of hydrogen, respectively, were obtained. These results confirmed the successful scale-up of a previous lab-scale device. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:1939 / 1946
页数:8
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