Anion- and Spacer-Directed Host-Guest Complexes of Bipyridine with Pyrogallol[4]arene

被引：13

作者：

Patil, Rahul S. ^{[1
]}

Kumari, Harshita ^{[1
,2
]}

Barnes, Charles L. ^{[1
]}

Atwood, Jerry L. ^{[1
]}

机构：

[1] Univ Missouri, Dept Chem, Columbia, MO 65211 USA

[2] Univ Cincinnati, James L Winkle Coll Pharm, Cincinnati, OH 45267 USA

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2015年 / 21卷 / 29期

关键词：

calixarenes; hydrogen bonding; nanocapsules; supramolecular chemistry; IONIC LIQUID; SOLID-STATE; ENCAPSULATION; NANOCAPSULE; FRAMEWORKS; FERROCENE; CAPSULES; DIMERS;

D O I：

10.1002/chem.201406574

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New oval-shaped capsular and bilayer-type hydrogen-bonded arrangements of C-propyl-ol-pyrogallol[4]arene (PgC3-OH) with bipyridine-type spacer complexes are reported here. These complexes are engineered by virtue of derivatization of C-alkyl tails of pyrogallol[4]arene and the use of divergent spacer ligands. Complexes of PgC3-OH, PgC3-OH with bpy (4,4-bipyridine) and PgC3-OH with bpa (1,2-bis(4-pyridyl)acetylene) have bilayer type arrangements; however, the use of hydrogen chloride causes protonation of bpy molecule, which is then entrapped flat within an offset oval-shaped dimeric hydrogen-bonded PgC3-OH nanocapsule. The presence of chloride anion in the crystal lattice controls the geometry of the resultant nanoassembly.

引用

页码：10431 / 10435

页数：5

共 50 条

[31] A conformationally adaptive macrocycle: conformational complexity and host-guest chemistry of zorb[4] arene
Yang, Liu-Pan
Lu, Song-Bo
Valkonen, Arto
Pan, Fangfang
Rissanen, Kari
Jiang, Wei
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2018, 14 : 1570 - 1577
[32] Interaction of the t-butylcalix[14]arene anion with ammonium cations in acetonitrile: Host-guest complexes or exo counterions? A molecular dynamics investigation
Fraternali, F
Wipff, G
JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, 1997, 28 (01) : 63 - 78
[33] Influence of the guest molecular size on the thermodynamic parameters of host-guest complexes between solid tert-butylcalix[4]arene and vapours of organic compounds
Gorbatchuk, VV
Tsifarkin, AG
Antipin, IS
Solomonov, BN
Konovalov, AI
MENDELEEV COMMUNICATIONS, 1999, (01) : 11 - 13
[34] Dissociation dynamics of host-guest interaction between substituted calix[4]-arene and 4-chloronitrobenzene
Kumar, Ashok
Sharma, Pratibha
Sharma, Pawan Kumar
Abuja, Monika
Matisz, Gergely
Kollar, Laszlo
Kunsagi-Mate, Sandor
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2016, 55 (03): : 304 - 308
[35] [(Ethylenediamine)Pt(uracilate)]4, a metal analogue of calix[4]arene.: Coordination and anion host-guest chemistry related to its conformational dynamics
Navarro, JAR
Janik, MBL
Freisinger, E
Lippert, B
INORGANIC CHEMISTRY, 1999, 38 (03) : 426 - 432
[36] Solvation effect of guest, supramolecular host, and host-guest compounds on the thermodynamic selectivity of calix(4)arene derivatives and soft metal cations
de Namor, AFD
Chahine, S
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (38): : 18096 - 18102
[37] Quasi-pentagonal shape of carboxylated pillar[6]arene in its host-guest crystalline complexes
Butkiewicz, H.
Kosiorek, S.
Sashuk, V.
Danylyuk, O.
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2022, 78 : E729 - E729
[38] Investigating the proton affinity of host vs. guest in zinc-seamed pyrogallol[4]arene nanocapsules
Kumari, Harshita
Mayhan, Collin M.
Atwood, Jerry L.
Deakyne, Carol A.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
[39] PHYS 320-Zinc-coordinated pyrogallol[4]arene assemblies: Host vs. guest protonation
Deakyne, Carol A.
Szabo, Tamas
Mayhan, Collin M.
Nussbaum, Sarah A.
Power, Nicholas P.
Dalgarno, Scott J.
Atwood, Jerry L.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 237
[40] Influence of photo-isomerisation on host-guest interactions in poly(azocalix[4]arene)s
Wiktorowicz, Szymon
Tenhu, Heikki
Aseyev, Vladimir
POLYMER CHEMISTRY, 2013, 4 (09) : 2898 - 2906

← 1 2 3 4 5 →