Band gap engineering in fluorescent conjugated microporous polymers

被引：290
作者：
Jiang, Jia-Xing
Trewin, Abbie
Adams, Dave J. [1 ]
Cooper, Andrew I.
机构：
[1] Univ Liverpool, Dept Chem, Liverpool, Merseyside, England
来源：
CHEMICAL SCIENCE | 2011年 / 2卷 / 09期
基金：
英国工程与自然科学研究理事会;
关键词：
HIGH-SURFACE-AREA; INTRINSIC MICROPOROSITY; ORGANIC FRAMEWORK; HYDROGEN STORAGE; NETWORKS; POLYMERIZATION; LUMINESCENT; PYRENE; POLYFLUORENES; CRYSTALLINE;
D O I：
10.1039/c1sc00329a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report here the synthesis of conjugated microporous polymers (CMPs) based on pyrene building units. The networks are both microporous and highly luminescent. The emission colour and resulting band gap can be fine tuned by introducing different comonomers and by varying the monomer distribution (statistical versus alternating). These materials might find applications in organic electronics, photocatalysis, optoelectronics, or in sensing technologies.
引用
收藏
页码：1777 / 1781
页数：5
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