Fabrication of a Nanosize-Pt-Embedded Membrane Electrode Assembly to Enhance the Utilization of Pt in Proton Exchange Membrane Fuel Cells

被引:6
作者
Choe, Junseok [1 ]
Kim, Doyoung [1 ]
Shim, Jinyong [1 ]
Lee, Inhae [1 ]
Tak, Yongsug [1 ]
机构
[1] Inha Univ, Dept Chem Engn, Inchon 402751, South Korea
关键词
PEMFC; Hydrophilic Channel; MEA; Nafion Membrane; Electrodeposition; NAFION; TRANSPORT;
D O I
10.1166/jnn.2011.4826
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A procedure to locate the Pt nanostructure inside the hydrophilic channel of a Nafion membrane was developed in order to enhance Pt utilization in PEMFCs. Nanosize Pt-embedded MEA was constructed by Cu electroless plating and subsequent Pt electrodeposition inside the hydrophilic channels of the Nafion membrane. The metallic Pt nanostructure fabricated inside the membrane was employed as an oxygen reduction catalyst for a PEMFC and facilitated effective use of the hydrophilic channels inside the membrane. Compared to the conventional MEA, a Pt-embedded MEA with only 68% Pt loading showed better PEMFC performance.
引用
收藏
页码:7141 / 7144
页数:4
相关论文
共 13 条
[1]   Efficient electrocatalyst utilization: Electrochemical deposition of Pt nanoparticles using nafion membrane as a template [J].
Chou, J ;
Jayaraman, S ;
Ranasinghe, AD ;
McFarland, EW ;
Buratto, SK ;
Metiu, H .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (14) :7119-7121
[2]   Electrolithographic investigations of the hydrophilic channels in Nafion membranes [J].
Chou, J ;
McFarland, EW ;
Metiu, H .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (08) :3252-3256
[3]   A comparison of different approaches to modelling the PEMFC catalyst layer [J].
Harvey, D. ;
Pharoah, J. G. ;
Karan, K. .
JOURNAL OF POWER SOURCES, 2008, 179 (01) :209-219
[4]   Nano structure of NAFION: a SAXS study [J].
Haubold, HG ;
Vad, T ;
Jungbluth, H ;
Hiller, P .
ELECTROCHIMICA ACTA, 2001, 46 (10-11) :1559-1563
[5]  
Hogarth MP, 2002, PLATIN MET REV, V46, P146
[6]   Interpretation of contrast in tapping mode AFM and shear force microscopy. A study of nafion [J].
James, PJ ;
Antognozzi, M ;
Tamayo, J ;
McMaster, TJ ;
Newton, JM ;
Miles, MJ .
LANGMUIR, 2001, 17 (02) :349-360
[7]   Observation of interface between Pt electrode and Nafion membrane [J].
Kanamura, K ;
Morikawa, H ;
Umegaki, T .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (02) :A193-A198
[8]   Relationship between carbon corrosion and positive electrode potential in a proton-exchange membrane fuel cell during start/stop operation [J].
Kim, Jutae ;
Lee, Junhee ;
Tak, Yongsug .
JOURNAL OF POWER SOURCES, 2009, 192 (02) :674-678
[9]  
Lee HD, 2007, KOREAN CHEM ENG RES, V45, P384
[10]   New DMFC anode structure consisting of platinum nanowires deposited into a Nafion membrane [J].
Liang, Z. X. ;
Zhao, T. S. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (22) :8128-8134