Structure and Absolute Configuration of Helosides A and B, New Saponins from Chamaelirium luteum

被引:11
作者
Challinor, Victoria L. [1 ]
Stuthe, Julia M. U. [1 ]
Bernhardt, Paul V. [1 ]
Lehmann, Reginald P. [2 ]
Kitching, William [1 ]
De Voss, James J. [1 ]
机构
[1] Univ Queensland, Sch Chem & Mol Biosci, Brisbane, Qld 4072, Australia
[2] Integria Healthcare, Brisbane, Qld 4113, Australia
来源
JOURNAL OF NATURAL PRODUCTS | 2011年 / 74卷 / 07期
关键词
STEROIDAL SAPONINS; PLANTS;
D O I
10.1021/np200100a
中图分类号
Q94 [植物学];
学科分类号
071001 ;
摘要
Investigation of Chamaelirium luteum roots led to the isolation of two new steroidal saponins, helosides A (1) and B (2), that contain a previously unreported aglycone, helogenin (3). Their structures and absolute configuration were elucidated through MS-MS, NMR, chemical degradation, and X-ray crystallography.
引用
收藏
页码:1557 / 1560
页数:4
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