Heterogenization of ruthenium porphyrin complexes in polymeric membranes:: Catalytic aziridination of styrenes

被引：20
|
作者：
Gallo, Emma [1 ,2 ]
Buonomenna, Maria Giovanna [3 ]
Vigano, Luca [1 ,2 ]
Ragaini, Fabio [1 ,2 ]
Caselli, Alessandro [1 ,2 ]
Fantauzzi, Simone [1 ,2 ]
Cenini, Sergio [1 ,2 ]
Drioli, Enrico [3 ]
机构：
[1] Univ Milan, Dipartimento Chim Inorgan Metallorgan & Analit, I-20133 Milan, Italy
[2] CNR, ISTM, I-20133 Milan, Italy
[3] Univ Calabria, Inst Membrane Technol, Natl Res Council Italy, ITM,CNR, I-87030 Arcavacata Di Rende, CS, Italy
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2008年 / 282卷 / 1-2期
关键词：
ruthenium; porphyrins; membranes; heterogeneous catalysis; aziridines;
D O I：
10.1016/j.molcata.2007.11.030
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In this paper we report the preparation of catalytic membranes having the complex Ru(4-(CF3)TPP)CO (1) (TPP=dianion of tetraphenylporphyrin) embedded in the perfluorinated polymer Hyflon AD60X and their use in the aziridination reaction of olefins by aryl azides. The heterogeneous membrane catalysts afforded high selectivities in aziridine (90-99%). In several cases the membrane was reused three times with a catalyst leaching <= 6% but no decrease in selectivities upon recycle was observed. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：85 / 91
页数：7
相关论文
共 50 条
  • [1] New ruthenium porphyrin polymeric membranes: Preparation and characterization
    Buonomenna, M. Giovanna
    Gallo, Emma
    Ragaini, Fabio
    Caselli, Alessandro
    Cenini, Sergio
    Drioli, Enrico
    APPLIED CATALYSIS A-GENERAL, 2008, 335 (01) : 37 - 45
  • [2] Aziridination of alkenes promoted by iron or ruthenium complexes
    Damiano, Caterina
    Intrieri, Daniela
    Gallo, Emma
    INORGANICA CHIMICA ACTA, 2018, 470 : 51 - 67
  • [3] The (porphyrin)ruthenium-catalyzed aziridination of olefins using aryl azides as nitrogen sources
    Fantauzzi, Simone
    Gallo, Emma
    Caselli, Alessandro
    Piangiolino, Cristiana
    Ragaini, Fabio
    Cenini, Sergio
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2007, 2007 (36) : 6053 - 6059
  • [4] Heterogenization of molybdenum complexes: Techniques and catalytic applications
    Rana, Lata
    APPLIED CATALYSIS A-GENERAL, 2023, 661
  • [5] ENANTIOSELECTIVE CATALYTIC EPOXIDATION OF STYRENES BY IODOSYLBENZENE USING CHIRAL RUTHENIUM(II) SCHIFF-BASE COMPLEXES
    KURESHY, RI
    KHAN, NH
    ABDI, SHR
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 96 (02) : 117 - 122
  • [6] Chiral porphyrin complexes of cobalt(II) and ruthenium(II) in catalytic cyclopropanation and amination reactions
    Caselli, Alessandro
    Gallo, Emma
    Ragaini, Fabio
    Ricatto, Federica
    Abbiati, Giorgio
    Cenini, Sergio
    INORGANICA CHIMICA ACTA, 2006, 359 (09) : 2924 - 2932
  • [7] Cyclopropanation of alkenes with diisopropyl diazomethylphosphonate catalysed by ruthenium porphyrin complexes
    Paul-Roth, C
    De Montigny, F
    Rehtoré, G
    Simonneaux, G
    Gulea, M
    Masson, S
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 201 (1-2) : 79 - 91
  • [8] Catalytic polymeric membranes: Preparation and application
    Ozdemir, Sibel Sain
    Buonomenna, Maria Giovanna
    Drioli, E.
    APPLIED CATALYSIS A-GENERAL, 2006, 307 (02) : 167 - 183
  • [9] Ruthenium (II) complexes in catalytic oxidation
    Aguirre, P
    Sariego, R
    Moya, SA
    JOURNAL OF COORDINATION CHEMISTRY, 2001, 54 (3-4) : 401 - 413
  • [10] Ruthenium(II) complexes of meso-tetrakis(4-cyanophenyl)porphyrin
    Reboucas, Julio S.
    James, Brian R.
    INORGANIC CHEMISTRY COMMUNICATIONS, 2013, 30 : 49 - 52
12345