NQR Study of AlBr3 Complexes with Dimethylsulfide

被引：0

作者：

Ishihara, Hideta ^{[1
]}

Sirahama, Tomoaki ^{[1
]}

Nakashima, Shouko ^{[1
]}

Terao, Hiromitsu ^{[2
]}

Yamada, Koji ^{[3
]}

机构：

[1] Saga Univ, Fac Culture & Educ, Saga 8408502, Japan

[2] Univ Tokushima, Fac Integrated Arts & Sci, Tokushima 7708502, Japan

[3] Nihon Univ, Coll Ind Technol, Chiba 2758576, Japan

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2011年 / 66卷 / 05期

关键词：

Br-81 and Al-27 NQR; Polymorphism; AlBr3 Complexes with (CH3)(2)S; NUCLEAR-QUADRUPOLE RESONANCE;

D O I：

10.5560/ZNB.2011.66b0541

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Br-81-Al-27 SEDOR as well as Br-81 NQR spectroscopy have been applied to the molecular complexes of AlBr3 with (CH3)(2)S. The formation of two kinds of complex compounds, [(CH3)(2)S](2)AlBr3 and [(CH3)(2)S]AlBr3, has been recognized. The compound [(CH3)(2)S](2)AlBr3 is a solid at ambient temperature, while the compound [(CH3)(2)S]AlBr3 is a liquid with a melting point of 287 K. The crystalline state of [(CH3)(2)S]AlBr3 shows a complex polymorphism consisting of Forms 1, 2 and 3 in which conformation isomers of [(CH3)(2)S]AlBr3 seem to exist. The structures of the complex compounds are discussed together with the results of ab initio MO calculations.

引用

收藏

页码：541 / 544

页数：4

相关论文

共 50 条

[31] Influence of the rf field inhomogeneity on nutation NQR spectra of spin 3/2 nuclei in powders [J].

Sinyavsky, N ;

Mackowiak, M ;

Velikite, N .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 1999, 54 (02) :153-158

[32] As-NMR/NQR study of pressure-induced superconductivity in CaFe2As2 [J].

Kawasaki, S. ;

Oka, T. ;

Tabuchi, T. ;

Wang, X. F. ;

Chen, X. H. ;

Zheng, Guo-qing .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2011, 72 (05) :501-504

[33] A portable Digital Multipulse NQR Spectrometer for the Study of the Sensory Properties, Structure and Defects in Layered Semiconductors [J].

Samila, A. P. ;

Politansky, L. F. ;

Hotra, O. Z. .

15TH INTERNATIONAL CONFERENCE ON ADVANCED TRENDS IN RADIOELECTRONICS, TELECOMMUNICATIONS AND COMPUTER ENGINEERING (TCSET - 2020), 2020, :98-101

[34] Sb-NQR study of PrOs4Sb12 under high pressure [J].

Kawasaki, Shinji ;

Katayama, Kouta ;

Nishiyama, Masahide ;

Kotegawa, Hisashi ;

Kobayashi, Tatsuo C. ;

Sugawara, Hitoshi ;

Kikuchi, Daisuke ;

Sato, Hideyuki ;

Zheng, Guo-qing .

JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2008, 77 :330-332

[35] 2D-nutation echo signals for very broad NQR lines (I=3/2) [J].

Glotova, O. N. ;

Korneva, I. P. ;

Sinyavskii, N. Ya. .

RUSSIAN PHYSICS JOURNAL, 2011, 54 (02) :257-259

[36] 2D off-resonance nutation NQR spectroscopy of spin 3/2 nuclei [J].

Mackowiak, M ;

Katowski, P .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 1998, 53 (6-7) :285-292

[37] 2D-nutation echo signals for very broad NQR lines (I = 3/2) [J].

O. N. Glotova ;

I. P. Korneva ;

N. Ya. Sinyavskii .

Russian Physics Journal, 2011, 54 :257-259

[38] NMR and NQR Study of Above-Room-Temperature Molecular Ferroelectrics Diisopropylammonium Chloride and Diisopropylammonium Perchlorate [J].

Apih, T. ;

Zagar, V. ;

Seliger, J. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2016, 120 (11) :6180-6189

[39] THE MUTUAL INFLUENCE OF LIGANDS IN SB(III) COMPLEX SALTS - AN X-RAY-DIFFRACTION AND NQR STUDY [J].

ISHIHARA, H ;

DOU, SQ ;

WEISS, A .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1991, 95 (06) :659-670

[40] Study of physical and chemical properties in some energetic materials from the tetrazole family by the 14N NQR [J].

Pirnat, Janez ;

Laznik, Janko ;

Jazbinsek, Vojko ;

Zagar, Veselko ;

Seliger, Janez ;

Klapoetke, Thomas ;

Trontelj, Zvonko .

NEW TRENDS IN RESEARCH OF ENERGETIC MATERIALS, PTS I & II, 13TH SEMINAR, 2010, :274-285

← 1 2 3 4 5 →