NQR Study of AlBr3 Complexes with Dimethylsulfide

被引：0

作者：

Ishihara, Hideta ^{[1
]}

Sirahama, Tomoaki ^{[1
]}

Nakashima, Shouko ^{[1
]}

Terao, Hiromitsu ^{[2
]}

Yamada, Koji ^{[3
]}

机构：

[1] Saga Univ, Fac Culture & Educ, Saga 8408502, Japan

[2] Univ Tokushima, Fac Integrated Arts & Sci, Tokushima 7708502, Japan

[3] Nihon Univ, Coll Ind Technol, Chiba 2758576, Japan

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2011年 / 66卷 / 05期

关键词：

Br-81 and Al-27 NQR; Polymorphism; AlBr3 Complexes with (CH3)(2)S; NUCLEAR-QUADRUPOLE RESONANCE;

D O I：

10.5560/ZNB.2011.66b0541

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Br-81-Al-27 SEDOR as well as Br-81 NQR spectroscopy have been applied to the molecular complexes of AlBr3 with (CH3)(2)S. The formation of two kinds of complex compounds, [(CH3)(2)S](2)AlBr3 and [(CH3)(2)S]AlBr3, has been recognized. The compound [(CH3)(2)S](2)AlBr3 is a solid at ambient temperature, while the compound [(CH3)(2)S]AlBr3 is a liquid with a melting point of 287 K. The crystalline state of [(CH3)(2)S]AlBr3 shows a complex polymorphism consisting of Forms 1, 2 and 3 in which conformation isomers of [(CH3)(2)S]AlBr3 seem to exist. The structures of the complex compounds are discussed together with the results of ab initio MO calculations.

引用

收藏

页码：541 / 544

页数：4

相关论文

共 50 条

[21] Intermetallic solid solution Fe1-xCoxGa3: Synthesis, structure, NQR study and electronic band structure calculations [J].

Verchenko, V. Yu ;

Likhanov, M. S. ;

Kirsanova, M. A. ;

Gippius, A. A. ;

Tkachev, A. V. ;

Gervits, N. E. ;

Galeeva, A. V. ;

Buettgen, N. ;

Kraetschmer, W. ;

Lue, C. S. ;

Okhotnikov, K. S. ;

Shevelkov, A. V. .

JOURNAL OF SOLID STATE CHEMISTRY, 2012, 194 :361-368

[22] The Geometrical Phase in the PEANUT Experiments for the NQR Spectroscopy for the Spins I = 3/2 [J].

N. Sinyavsky ;

N. Kostrikova .

Applied Magnetic Resonance, 2016, 47 :63-76

[23] The Geometrical Phase in the PEANUT Experiments for the NQR Spectroscopy for the Spins I=3/2 [J].

Sinyavsky, N. ;

Kostrikova, N. .

APPLIED MAGNETIC RESONANCE, 2016, 47 (01) :63-76

[24] Study of As-Sb-Se chalcogenide glasses by NQR and EPR spectroscopy methods [J].

Glotova, Olga N. ;

Korneva, Irina P. ;

Sinyavsky, Nikolay Ya. ;

Dobosz, Bernadeta ;

Krzyminiewski, Ryszard ;

Jadzyn, Maciej ;

Ostafin, Michal ;

Nogaj, Boleslaw .

CENTRAL EUROPEAN JOURNAL OF PHYSICS, 2011, 9 (02) :387-391

[25] Study of relationship between NQR signal amplitudes and nitrogen contents in explosive simulants [J].

Hao, Fenglong ;

Xu, Gengguang ;

Huang, Xueyi .

MEASUREMENT TECHNOLOGY AND ENGINEERING RESEARCHES IN INDUSTRY, PTS 1-3, 2013, 333-335 :336-342

[26] Powder Zeeman NQR study on the absorption forms for nuclear spin 5/2 [J].

Ege, O ;

Nishijima, S ;

Kimura, E ;

Akiyama, H ;

Hamai, S ;

Negita, H .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 1998, 53 (6-7) :314-317

[27] NQR and NMR study of hydrogen bonding interactions in anhydrous and monohydrated guanine cluster model: A computational study [J].

M. Monajjemi ;

B. Honarparvar ;

S. M. Nasseri ;

M. Khaleghian .

Journal of Structural Chemistry, 2009, 50 :67-77

[28] NQR and NMR study of hydrogen bonding interactions in anhydrous and monohydrated guanine cluster model: A computational study [J].

Monajjemi, M. ;

Honarparvar, B. ;

Nasseri, S. M. ;

Khaleghian, M. .

JOURNAL OF STRUCTURAL CHEMISTRY, 2009, 50 (01) :67-77

[29] As-NQR study of superconductivity in LaRAsO1-xFx (R=Fe and Ni) [J].

Oka, T. ;

Tabuchi, T. ;

Li, Z. ;

Kawasaki, S. ;

Chen, G. F. ;

Luo, J. L. ;

Wang, N. L. ;

Zheng, Guo-qing .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2011, 72 (05) :497-500

[30] NMR/NQR study of the quadrupole orders in binary uranium-palladium intermetallic compound [J].

Fujimoto, Tatsuya ;

Haga, Yoshinori ;

Sakai, Hironori ;

Tokunaga, Yo ;

Kambe, Shinsaku ;

Onuki, Yoshichika .

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2007, 310 (02) :746-747

← 1 2 3 4 5 →