Defect engineering in metal-organic frameworks: a new strategy to develop applicable actinide sorbents

被引：183
作者：
Yuan, Liyong [1 ]
Tian, Ming [1 ,2 ]
Lan, Jianhui [1 ]
Cao, Xingzhong [1 ]
Wang, Xiaolin [3 ]
Chai, Zhifang [1 ,4 ]
Gibson, John K. [5 ]
Shi, Weiqun [1 ]
机构：
[1] Chinese Acad Sci, Inst High Energy Phys, Lab Nucl Energy Chem, Beijing 100049, Peoples R China
[2] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Hunan, Peoples R China
[3] China Acad Engn Phys, Inst Nucl Phys & Chem, Mianyang 621900, Sichuan, Peoples R China
[4] Soochow Univ, Sch Radiol & Interdisciplinary Sci, Suzhou 215123, Peoples R China
[5] Lawrence Berkeley Natl Lab, Chem Sci Div, Berkeley, CA 94720 USA
来源：
CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 04期
基金：
中国国家自然科学基金;
关键词：
URANIUM EXTRACTION; UIO-66;
D O I：
10.1039/c7cc07527h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The preliminary results described here show that the adsorbability of uranyl ions by a highly stable MOF UiO-66 can be drastically enhanced by tailoring the missing-linker defects in this MOF. The combination of defect-induced functionality improvement with the acid-resistant nature of UiO-66 substantiates the applicability of this material for actinide capture from acidic media.
引用
收藏
页码：370 / 373
页数：4
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