Palladium doping of magic gold cluster Au38(SC2H4Ph)24: formation of Pd2Au36(SC2H4Ph)24 with higher stability than Au38(SC2H4Ph)24

被引：165

作者：

Negishi, Yuichi ^{[1
]}

Igarashi, Kozue ^{[1
]}

Munakata, Kenta ^{[1
]}

Ohgake, Wataru ^{[1
]}

Nobusada, Katsuyuki ^{[2
]}

机构：

[1] Tokyo Univ Sci, Fac Sci, Dept Appl Chem, Shinjuku Ku, Tokyo 1628601, Japan

[2] Natl Inst Nat Sci, Inst Mol Sci, Dept Theoret & Computat Mol Sci, Okazaki, Aichi 4448585, Japan

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 05期

关键词：

ELECTRONIC-STRUCTURE; CRYSTAL-STRUCTURE; LUMINESCENCE; NANOCLUSTERS;

D O I：

10.1039/c1cc15765e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A phenylethanethiolate-protected Pd2Au36(SC2H4Ph)(24) cluster, which is a two-Pd atom-doped cluster of the well studied magic gold cluster Au-38(SC2H4Ph)(24), was synthesized in high purity and its stability was investigated. The results demonstrate that Pd2Au36(SC2H4Ph)(24) is more stable than Au-38(SC2H4Ph)(24) against degradation in solution and core etching by thiols.

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页码：660 / 662

页数：3

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