Nanosegregation in arene-perfluoroarene π-systems for hybrid layered Dion-Jacobson perovskites

被引：14

作者：

Almalki, Masaud ^{[1
]}

Ducinskas, Algirdas ^{[1
,2
]}

Carbone, Loi C. ^{[1
]}

Pfeifer, Lukas ^{[1
]}

Piveteau, Laura ^{[3
]}

Luo, Weifan ^{[4
]}

Lim, Ethan ^{[4
]}

Gaina, Patricia A. ^{[4
,6
]}

Schouwink, Pascal A. ^{[5
]}

Zakeeruddin, Shaik M. ^{[1
]}

Milic, Jovana, V ^{[1
,4
]}

Gratzel, Michael ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Chem & Chem Engn, Lab Photon & Interfaces, CH-1015 Lausanne, Switzerland

[2] Max Planck Inst Solid State Res, D-70569 Stuttgart, Germany

[3] Ecole Polytech Fed Lausanne, Inst Chem & Chem Engn, CH-1015 Lausanne, Switzerland

[4] Univ Fribourg, Adolphe Merkle Inst, CH-1700 Fribourg, Switzerland

[5] Ecole Polytech Fed Lausanne, Inst Chem & Chem Engn, CH-1951 Sion, Switzerland

[6] Alexandru Ioan Cuza Univ, Fac Chem, Bd Carol I 11, Iasi 700506, Romania

来源：

NANOSCALE | 2022年 / 14卷 / 18期

关键词：

HALIDE PEROVSKITES; CATION; DYNAMICS; ION;

D O I：

10.1039/d1nr08311b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Layered hybrid perovskites are based on organic spacers separating hybrid perovskite slabs. We employ arene and perfluoroarene moieties based on 1,4-phenylenedimethylammonium (PDMA) and its perfluorinated analogue (F-PDMA) in the assembly of hybrid layered Dion-Jacobson perovskite phases. The resulting materials are investigated by X-ray diffraction, UV-vis absorption, photoluminescence, and solid-state NMR spectroscopy to demonstrate the formation of layered perovskite phases. Moreover, their behaviour was probed in humid environments to reveal nanoscale segregation of layered perovskite species based on PDMA and F-PDMA components, along with enhanced stabilities of perfluoroarene systems, which is relevant to their application.

引用

页码：6771 / 6776

页数：6

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