Growth and characterization of a new nonlinear optical serniorganic lithium paranitropheno late trihydrate (NO2-C6H4OLi-3H2O) single crystal

被引:40
作者
Boaz, BM [1 ]
Rajesh, AL [1 ]
Raja, SXJ [1 ]
Das, SJ [1 ]
机构
[1] Loyola Coll, Dept Phys, Madras 600034, Tamil Nadu, India
关键词
nonlinear optical property; single crystal XRD data; solution grown crystal; semiorganic lithium paranitrophenolate trjhydrate crystal; absorption spectra;
D O I
10.1016/j.jcrysgro.2003.10.041
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Lithium paranitrophenolate trihydrate (NPLi . 3H(2)O) is a new semiorganic nonlinear optical crystal. It has a d(eff) of about 2 times that of Lithium niobate. Large single crystals of size 16 x 9 x 6 mm(3) are obtained by isothermal solvent evaporation and the grown crystals are characterized using single crystal X-ray diffractometry (XRD), Fourier transform infra-red (FTIR), DRS-UV and solubility measurements. XRD analysis confirms the molecular formula and structure of the crystal. The DRS-UV spectrum shows good optical transparency in the entire visible region. The SHG efficiency of the crystal is measured by Kurtz's powder method using Nd-YAG Laser. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:531 / 535
页数:5
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