Catalytic oxidative cleavage of olefins promoted by osmium tetroxide and hydrogen peroxide

被引：46

作者：

Hart, Stewart R. ^{[1
]}

Whitehead, Daniel C. ^{[1
]}

Travis, Benjamin R. ^{[1
]}

Borhan, Babak ^{[1
]}

机构：

[1] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2011年 / 9卷 / 13期

关键词：

ADIPIC ACID; OZONOLYSIS; LACTONIZATION; OZONE; OXONE; BONDS; WATER;

D O I：

10.1039/c0ob01189d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hydrogen peroxide was employed as the terminal oxidant in the osmium tetroxide mediated oxidative cleavage of olefins, producing the corresponding aldehyde and ketone products. Aryl olefins are cleaved in good to excellent yield regardless of arene electronics. Alkyl olefins cleave in moderate to good yield for di- and tri-substituted alkenes.

引用

页码：4741 / 4744

页数：4

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