Photocatalytic production of hydrogen peroxide through selective two-electron reduction of dioxygen utilizing amine-functionalized MIL-125 deposited with nickel oxide nanoparticles

被引：115

作者：

Isaka, Yusuke ^{[1
]}

Kondo, Yoshifumi ^{[1
]}

Kawase, Yudai ^{[1
]}

Kuwahara, Yasutaka ^{[1
,2
]}

Mori, Kohsuke ^{[1
,2
,3
]}

Yamashita, Hiromi ^{[1
,2
]}

机构：

[1] Osaka Univ, Grad Sch Engn, 2-1 Yamadaoka, Suita, Osaka 5650871, Japan

[2] Kyoto Univ, Elements Strategy Initiat Catalysts & Batteries E, Kyoto 6158520, Japan

[3] JST, PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama 3320012, Japan

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 67期

基金：

日本学术振兴会;

关键词：

METAL-ORGANIC FRAMEWORK; VISIBLE-LIGHT; MOLECULAR-OXYGEN; FUEL-CELL; CRYSTAL-STRUCTURE; CATHODE MATERIAL; WATER STABILITY; SOLAR FUEL; CENTER-DOT; TIO2;

D O I：

10.1039/c8cc02679c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photocatalytic H2O2 production via two-electron reduction of O-2 was realized by visible-light irradiation of a metal-organic framework, MIL-125-NH2, in the presence of TEOA and benzylalcohol. Deposition of NiO nanoparticles onto MIL-125-NH2 dramatically enhanced the catalytic activity. Further studies suggested that fast disproportionation of the O-2(center dot-) intermediate to H2O2 resulted in the enhancement.

引用

页码：9270 / 9273

页数：4

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