Fabrication of polyrotaxane and graphene nanoplate composites with high thermal conductivities

被引:7
作者
Iida, Masaki [1 ,2 ]
Goto, Taku [1 ,2 ]
Mayumi, Koichi [1 ,2 ]
Maeda, Rina [1 ]
Hatakeyama, Kazuto [2 ]
Ito, Tsuyohito [1 ,2 ]
Shimizu, Yoshiki [2 ]
Ito, Kohzo [1 ]
Hakuta, Yukiya [2 ]
Terashima, Kazuo [1 ,2 ]
机构
[1] Univ Tokyo, Grad Sch Frontier Sci, Dept Adv Mat Sci, 5-1-5 Kashiwanoha, Kashiwa, Chiba 2778561, Japan
[2] Natl Inst Adv Ind Sci & Technol, AIST UTokyo Adv Operando Measurement Technol Open, 5-1-5 Kashiwanoha, Kashiwa, Chiba 2778561, Japan
基金
日本学术振兴会;
关键词
composites; fillers; mechanical properties; polyrotaxanes; thermal properties; NANOCOMPOSITE; PARTICLES;
D O I
10.1002/pc.26246
中图分类号
TB33 [复合材料];
学科分类号
摘要
In recent years, rapid progress in the development of flexible electronic devices has increased the demand for materials with low Young's modulus and high thermal conductivities. In this study, we successfully fabricated such composites with polyrotaxane (PR) by applying highly concentrated graphene nanoplates (GNPs). A high thermal conductivity of 25 W m(-1) K-1 was achieved along the in-plane direction of the composite while maintaining a low Young's modulus of 147 MPa at 35 vol% of GNPs. This thermal conductivity is higher than those achieved with PR composites containing 56 vol% of hexagonal boron nitride and 37 vol% of aligned carbon nanofiber/carbon nanotubes.
引用
收藏
页码:5556 / 5563
页数:8
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