A mixed-valent niobium oxysulfide, La2Nb3S2O8

被引：6

作者：

Cario, L ^{[1
]}

Kabbour, H ^{[1
]}

Guillot-Deudon, C ^{[1
]}

Meerschaut, A ^{[1
]}

机构：

[1] Inst Mat Jean Rouxel, F-44322 Nantes, France

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2003年 / 59卷

关键词：

D O I：

10.1107/S0108270103009570

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dilanthanum triniobium disulfide octaoxide, La2Nb3S2O8, crystallizes in the orthorhombic space group Pnnm and is isostructural with the Ln(2)Ta(3)X(2)O(8) (Ln=La, Ce, Pr and Nd, and X=S and Se) family of tantalum compounds. Nb4+ and Nb5+ ions co-exist in the structure and occupy different crystallographic sites. While the Nb4+ ions are found in mixed oxygen and sulfur octahedra, the Nb5+ ions are found in oxygen-only octahedra.

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页码：I55 / I56

页数：2

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