Determination of acidity of ionic liquids and alkylation of isobutane with butene by chloroaluminate ionic liquids

被引：0
作者：
Yang, YL [1 ]
Wang, XH [1 ]
Kou, Y [1 ]
机构：
[1] Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
来源：
CHINESE JOURNAL OF CATALYSIS | 2004年 / 25卷 / 01期
关键词：
ionic liquid; acidity; pyridine probe; infrared spectroscopy; isobutane; butene; alkylation;
D O I：
暂无
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A novel method was established to determine the acidity of ionic liquids by using pyridine as IR spectroscopic probe. This method can be used to identify the Bronsted/Lewis acidity of ionic liquids, and meanwhile roughly delineate the strength of the Lewis acidity. [bmim]Cl/AlCl3 was used as a catalyst in the alkylation of isobutane with butene. The effects of operating variables were investigated and optimized. Under the optimized operation conditions, the catalytic performance of the ionic liquid is comparable with that of H2SO4. In addition, the ionic liquid can be easily separated from the products and reused directly without any treatment for about 10 times.
引用
收藏
页码：60 / 64
页数：5
相关论文
共 50 条
  • [1] Effects of additives on the properties of chloroaluminate ionic liquids catalyst for alkylation of isobutane and butene
    Huang, CP
    Liu, ZC
    Xu, CM
    Chen, BH
    Liu, YF
    APPLIED CATALYSIS A-GENERAL, 2004, 277 (1-2) : 41 - 43
  • [2] Alkylation of isobutane with butene catalyzed by deep eutectic ionic liquids
    Wang, Hongyan
    Ma, Song
    Zhou, Zhimao
    Li, Minjie
    Wang, Hui
    FUEL, 2020, 269
  • [3] Research progress in ionic liquids catalyzed isobutane/butene alkylation
    Panxue Gan
    Shengwei Tang
    ChineseJournalofChemicalEngineering, 2016, 24 (11) : 1497 - 1504
  • [4] Research progress in ionic liquids catalyzed isobutane/butene alkylation
    Gan, Panxue
    Tang, Shengwei
    CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2016, 24 (11) : 1497 - 1504
  • [5] Determination of acidity of ionic liquids and alkylation of diphenyl oxide with dodecene catalyzed by ionic liquids
    Piao, LY
    Fu, X
    Yang, YL
    Tao, GH
    Kou, Y
    CHINESE JOURNAL OF CATALYSIS, 2004, 25 (01) : 44 - 48
  • [6] Isobutane/2-butene alkylation catalyzed by chloroaluminate ionic liquids in the presence of aromatic additives
    Zhang, Jie
    Huang, Chongpin
    Chen, Biaohua
    Ren, Pengju
    Pu, Min
    JOURNAL OF CATALYSIS, 2007, 249 (02) : 261 - 268
  • [7] Chlorogallate(Ⅲ) ionic liquids: Synthesis, acidity determination and their catalytic performances for isobutane alkylation
    XING XueQi1
    Science China(Chemistry) , 2012, (08) : 1542 - 1547
  • [8] Chlorogallate(III) ionic liquids: Synthesis, acidity determination and their catalytic performances for isobutane alkylation
    XueQi Xing
    GuoYing Zhao
    JianZhong Cui
    Science China Chemistry, 2012, 55 : 1542 - 1547
  • [9] Chlorogallate(III) ionic liquids: Synthesis, acidity determination and their catalytic performances for isobutane alkylation
    Xing XueQi
    Zhao GuoYing
    Cui JianZhong
    SCIENCE CHINA-CHEMISTRY, 2012, 55 (08) : 1542 - 1547
  • [10] Improved 1-butene/isobutane alkylation with acidic ionic liquids and tunable acid/ionic liquid mixtures
    Tang, Shengwei
    Scurto, Aaron M.
    Subramaniam, Bala
    JOURNAL OF CATALYSIS, 2009, 268 (02) : 243 - 250
12345