Cation-exchange resins in the hydroformylation-acetalization tandem reaction

被引：10

作者：

Gorbunov, D. N. ^{[1
]}

Shchukina, T. V. ^{[2
]}

Kardasheva, Yu. S. ^{[1
]}

Sinikova, N. A. ^{[1
]}

Maksimov, A. L. ^{[1
]}

Karakhanov, E. A. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Fac Chem, Moscow, Russia

[2] Moscow MV Lomonosov State Univ, Grad Sch Innovat Business, Moscow, Russia

来源：

PETROLEUM CHEMISTRY | 2016年 / 56卷 / 08期

关键词：

hydroformylation; acetalization; tandem process; catalysis; solid acids; GLYCEROL; CATALYSIS;

D O I：

10.1134/S0965544116080065

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cation-exchange resins in the acid form (Amberlyst-16, Wofatit KPS 200, Nafion, KU-2) have been tested as the acidic component of a catalyst system for the hydroformylation-acetalization tandem process. It has been shown that the hydroformylation of octene-1 in the presence of ethylene glycol and glycerol using a catalyst system comprising a rhodium complex, a phosphine ligand, and a solid acid leads to the formation of acetals with a yield of up to 99%.

引用

页码：711 / 716

页数：6

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