Helicity inversion in responsive foldamers induced by achiral halide ion guests

被引：289
作者：
Meudtner, Robert M. [1 ]
Hecht, Stefan [1 ]
机构：
[1] Humboldt Univ, Dept Chem, D-12489 Berlin, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 26期
关键词：
chirality; click chemistry; foldamers; helical polymers; helix inversion;
D O I：
10.1002/anie.200800796
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Graph Presented) A surprising about-face: Click chemistry was used for the efficient synthesis of a newclass of foldamers, referred to as clickamers, that display unusual folding and recognition properties. In the presence of halide ions - achiral species - they undergo an unprecedented helix inversion. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：4926 / 4930
页数：5
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