Color-tunable and white-light emitting lanthanide complexes based on (CexEuyTb1-x-y)2(BDC)3(H2O)4

Ce3+, Eu3+ and Tb3+ complexes were synthesized through facile and mild approaches with terephthalic acid (H2BDC) as the ligand. Their chemical compositions were determined as (CexEuyTb1-x-y)(2)(BDC)(3)(H2O)(4) by elemental analysis (EA), Fourier transform infrared (FTIR) spectra and X-ray diffraction (XRD) measurements. Fluorescent properties of the as-synthesized complexes were investigated by changing the molar ratio of Ce3+, Tb3+ and Eu3+ ions, and the optimized ratio of 3.0:2.0:0.15 for Ce3+: Tb3+: Eu3+ in the complex was determined for white-light emission. Tuning on the emitting color was realized by adjusting the ratio among lanthanide ions, indicating the energy transfer process inside the complex. It was found that Tb3+ could sensitize the fluorescence of Eu3+ while its own fluorescence was quenched by the latter ion, and concentration quenching of Ce3+ was also observed. Fairly good thermal stability and oxidation resistance of the as-synthesized complexes were also demonstrated. (C) 2011 Elsevier B.V. All rights reserved.