Preparation of alkyl aryl sulfides from alcohols and 2-sulfanylbenzothiazole by a new type of oxidation-reduction condensation using aryl diphenylphosphinite and benzoquinone derivatives

被引：10

作者：

Kuroda, Kiichi ^{[1
]}

Hayashi, Yujiro ^{[1
]}

Mukaiyama, Teruaki ^{[2
]}

机构：

[1] Tokyo Univ Sci, Dept Ind Chem, Fac Engn, Shinjuku Ku, Tokyo 1628601, Japan

[2] Kitasato Inst, Ctr Basic Res, Kita Ku, Tokyo 1140003, Japan

来源：

CHEMISTRY LETTERS | 2008年 / 37卷 / 06期

关键词：

D O I：

10.1246/cl.2008.592

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A method for the preparation of alkyl aryl sulfides from alcohols and 2-sulfanylbenzothiazole by a new type of oxidation-reduction condensation using phenyl diphenylphosphinite and 2,6-dimethoxy-1,4-benzoquinone is described. In this reaction, the chiral alcohols are converted into the corresponding chiral sulfides with almost complete inversion of configurations under mild and neutral conditions.

引用

页码：592 / 593

页数：2

共 21 条

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