Rational Design of Metal Nanoframes for Catalysis and Plasmonics

被引:128
作者
Fang, Zhicheng [1 ,2 ,3 ]
Wang, Youcheng [1 ,2 ,3 ]
Liu, Chenxuan [1 ,2 ,3 ]
Chen, Sheng [1 ,2 ,3 ]
Sang, Wei [1 ,2 ,3 ]
Wang, Chao [4 ]
Zeng, Jie [1 ,2 ,3 ]
机构
[1] Univ Sci & Technol China, Chinese Acad Sci, Ctr Adv Nanocatalysis CAN USTC, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China
[2] Univ Sci & Technol China, Chinese Acad Sci, Ctr Adv Nanocatalysis CAN USTC, Key Lab Strongly Coupled Quantum Matter Phys, Hefei 230026, Anhui, Peoples R China
[3] Univ Sci & Technol China, Dept Chem Phys, Hefei 230026, Anhui, Peoples R China
[4] Johns Hopkins Univ, Dept Chem & Biomol Engn, Baltimore, MD 21218 USA
关键词
metal nanoframes; catalysis; plasmonics; GALVANIC REPLACEMENT REACTIONS; NANOSCALE OPTICAL BIOSENSOR; RANGE DISTANCE DEPENDENCE; OXYGEN REDUCTION; GOLD NANOFRAMES; CONCAVE NANOCUBES; CUBIC NANOFRAMES; PT-ALLOY; SILVER; NANOSTRUCTURES;
D O I
10.1002/smll.201402799
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Recently, metal nanoframes have received increased attention due to their unique spatial and physicochemical, e.g., catalytic and plasmonic properties. So far, a variety of synthetic procedures have been developed to fabricate metal nanoframes with different shapes, sizes and compositions. Typical synthesis of metal nanoframes involves two stages: 1) formation of solid nanocrystals and 2) hollowing out the interiors and side faces. In this review, solution-phase synthetic strategies are summarized, based on galvanic replacement reactions, oxidative etching, the Kirkendall effect, electrodeposition, and template-assisted growth, as well as one-pot synthesis. Their potential applications in catalysis and optical sensing are overviewed as well.
引用
收藏
页码:2593 / 2605
页数:13
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