A chiral porous 3D metal-organic framework with an unprecedented 4-connected network topology

被引：63
|
作者：
Wu, CD [1 ]
Lin, WB [1 ]
机构：
[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA
来源：
CHEMICAL COMMUNICATIONS | 2005年 / 29期
关键词：
D O I：
10.1039/b505916j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel homochiral 3D metal-organic framework [CdL2(H2O)(2)][ClO4](2)center dot 2DMF center dot 3EtOH center dot 5/3H(2)O, 1, (L = (R)- 6,6'-dichloro- 2,2'-diethoxy-1,1'-binaphthyl-4,4'-bipyridine) exhibits an unprecedented 4-connected network topology owing to the cis- configuration of the Cd coordination and possesses permanent porosity as demonstrated by TGA, XRPD, and CO2 adsorption isotherm studies.
引用
收藏
页码：3673 / 3675
页数：3
相关论文
共 50 条
  • [41] 3D porous metal-organic framework exhibiting selective adsorption of water over organic solvents
    Gu, Jin-Zhong
    Lu, Wen-Guan
    Jiang, Long
    Zhou, Hong-Cai
    Lu, Tong-Bu
    INORGANIC CHEMISTRY, 2007, 46 (15) : 5835 - 5837
  • [42] Urothermal in situ ligand synthesis to fabricate a metal-organic framework with (3,4)-connected tfi topology
    Yang, Hui
    Li, Tie Hu
    Kang, Yao
    Wang, Fei
    INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (11) : 1695 - 1697
  • [43] An unprecedented (4,10)-connected porous metal-organic framework containing two rare large secondary building units (SBUs)
    Zhong, Di-Chang
    Deng, Ji-Hua
    Luo, Xu-Zhong
    Lu, Tong-Bu
    Wang, Ke-Jun
    CRYSTENGCOMM, 2012, 14 (05): : 1538 - 1541
  • [44] Microporous 3-D chiral metal-organic framework with a quartzlike topology based on an achiral building unit
    Wu, Yapan
    Li, Dongsheng
    Fu, Feng
    Tang, Long
    Wang, Jijiang
    Yang, Xiao Gang
    JOURNAL OF COORDINATION CHEMISTRY, 2009, 62 (16) : 2665 - 2674
  • [45] 4-Connected Cobalt-Based 3D Framework with a High Affinity for Acetylene
    Wu, Nana
    Li, Qian
    Li, Jia
    Wu, Dapeng
    Li, Yanshuo
    INORGANIC CHEMISTRY, 2020, 59 (14) : 9461 - 9464
  • [46] A 4-connected anionic metal-organic nanotube constructed from indium isophthalate
    Bu, Fei
    Xiao, Shou-Jun
    CRYSTENGCOMM, 2010, 12 (11): : 3385 - 3387
  • [47] New Metal-Organic Framework with Uninodal 4-Connected Topology Displaying Interpenetration, Self-Catenation, and Second-Order Nonlinear Optical Response
    Liu, Tian-Fu
    Lue, Jian
    Guo, Zhengang
    Proserpio, Davide M.
    Cao, Rong
    CRYSTAL GROWTH & DESIGN, 2010, 10 (04) : 1489 - 1491
  • [48] Homochiral Metal-Organic Framework with Intrinsic Chiral Topology and Helical Channels
    Wang, Fei
    Fu, Hong-Ru
    Zhang, Jian
    CRYSTAL GROWTH & DESIGN, 2015, 15 (04) : 1568 - 1571
  • [49] Synthesis and crystal structure of novel 3D porous metal-organic framework material for photocatalysis
    Thrickmorton, Cristina
    Yan, Bangbo
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 257
  • [50] A polyoxometalate-encapsulated 3D porous metal-organic pseudo-rotaxane framework
    Pang, Hai-jun
    Peng, Jun
    Zhang, Chun-jing
    Li, Yang-guang
    Zhang, Peng-peng
    Ma, Hui-yuan
    Su, Zhong-min
    CHEMICAL COMMUNICATIONS, 2010, 46 (28) : 5097 - 5099
12345